Linear, graft, and beyond: multiblock copolymers as next-generation compatibilizers

JL Self, AJ Zervoudakis, X Peng, WR Lenart… - JACs Au, 2022 - ACS Publications
Properly addressing the global issue of unsustainable plastic waste generation and
accumulation will require a confluence of technological breakthroughs on various fronts …

Mechanically Robust, Self-Repairable, Shape Memory and Recyclable Ionomeric Elastomer Composites with Renewable Lignin via Interfacial Metal–Ligand …

G Zhang, C Tian, J Shi, X Zhang, J Liu… - … Applied Materials & …, 2022 - ACS Publications
Lignin, the most abundant aromatic polymer in nature, is one of the most promising
renewable feedstocks for value-added polymer products. However, it is challenging to …

Biobased Thermoplastic Elastomer Based on an SMS Triblock Copolymer Prepared via RAFT Polymerization in Aqueous Medium

U Kalita, S Samanta, SL Banerjee, NC Das… - …, 2021 - ACS Publications
In recent years, there has been a great interest in preparing polymers from bioresources, as
this practice has several advantages over petrobased polymers. Thermoplastic elastomers …

Tunable thermoplastic elastomer gels derived from controlled-distribution triblock copolymers with crystallizable endblocks

NT Hames, D Balsbough, J Yan, S Wu, X Zuo… - Materials …, 2023 - pubs.rsc.org
Thermoplastic elastomers (TPEs), a commercially important category of triblock copolymers,
are employed alone or upon physical modification with a midblock-selective oil (to form TPE …

Macromolecular additives to turn a thermoplastic elastomer into a self-healing material

L Simonin, G Falco, S Pensec, F Dalmas… - …, 2021 - ACS Publications
Self-healing allows increasing the service life of materials by overcoming some issues
caused by mechanical failures. We propose a new concept to impart room-temperature self …

One-pot synthesis of supertough, sustainable polyester thermoplastic elastomers using block-like, gradient copolymer as soft midblock

W Zhao, C Li, X Yang, J He, X Pang, Y Zhang… - CCS …, 2022 - chinesechemsoc.org
It remains challenging to synthesize supertough thermoplastic elastomers (TPEs) since the
stretchability and tensile strength are mutually exclusive. Here, we report a one-pot strategy …

High-Performance Stimulus-Healable Sustainable Multiblock Copolymer Elastomers with Magnetothermal and Photothermal Properties

P Tang, C Wen, Y Xing, C Yin, H Tai, J Feng… - …, 2023 - ACS Publications
Sustainable elastomers with high strength and unique functions are highly desired yet
challenging. In this work, multiblock copolymer elastomers (MBCPEs) were synthesized by …

Improved Elastic Recovery from ABC Triblock Terpolymers

KR Albanese, JR Blankenship, T Quah, A Zhang… - ACS Polymers …, 2023 - ACS Publications
The promise of ABC triblock terpolymers for improving the mechanical properties of
thermoplastic elastomers is demonstrated by comparison with symmetric ABA/CBC analogs …

Architectural Design of Block Copolymers

Z Xu, Q Dong, W Li - Macromolecules, 2024 - ACS Publications
Highly designable architectures of polymers endow the same polymer with different
properties. In principle, diverse architectures should enrich the self-assembly behavior of …

Characterization of Controlled-Distribution Hydrogenated Styrenic Block Copolymers by Nuclear Magnetic Resonance Spectroscopy

J Yang, DS Germack, RJ Spontak - ACS Applied Polymer …, 2023 - ACS Publications
As the need for engineered soft materials continues to grow, block polymers possessing
tailored chain architectures and chemical sequences are being upscaled from the laboratory …