Five-coordinate transition metal complexes and the value of τ 5: observations and caveats

AG Blackman, EB Schenk, RE Jelley, EH Krenske… - Dalton …, 2020 - pubs.rsc.org
The τ5 parameter, first proposed by Addison and coworkers, is the principal measure of the
geometry of five-coordinate transition metal complexes, with τ5= 0 said to describe a perfect …

A comparison study of aliphatic and aromatic structure directing agents influencing the crystal and electronic structures, and properties of iodoplumbate hybrids: water …

GN Liu, JR Shi, XJ Han, X Zhang, K Li, J Li… - Dalton …, 2015 - pubs.rsc.org
The introduction of the aliphatic amines en (ethylenediamine), aep (N-(2-aminoethyl)
piperazine) and tepa (tetraethylenepentamine), and the aromatic species 2, 2′-bipy (2, 2 …

Coordination modes of azide in cadmium azide complexes: A review of properties and applications

B Mirtamizdoust, A Karamad - Inorganic Chemistry Communications, 2023 - Elsevier
Azide serves as a flexible bridge for cadmium, with various modes such as single or double
bridges μ 1, 3-N 3 (EE), μ 1, 1-N 3 (EO), and (μ 1, 3-N 3)(μ 1, 1-N 3)(EE/EO), triple bridges μ …

Synthesis, Crystal Structure, Hirshfeld Surface Analysis of bis(N,N-Diethylenediamine)Cadmium(II)] Dichloride

N Dege - Journal of Structural Chemistry, 2023 - Springer
A new Cd (II) complex, bis [(N, N-diethylenediamine) cadmium (II)] dichloride,
C12H32CdCl2N4, was synthesized by the reaction between cadmium (II) chloride …

Exogenous spermidine enhanced Pb tolerance in Salix matsudana by promoting Pb accumulation in roots and spermidine, nitric oxide, and antioxidant system levels …

C Tang, J Song, X Hu, X Hu, Y Zhao, B Li, D Ou… - Ecological …, 2017 - Elsevier
The protective role of spermidine addition in media to Salix matsudana exposed to Pb was
investigated by a hydroponic experiment in this study. The application of spermidine …

Variation in molecular and crystalline architectures of di-and poly-nuclear cadmium (II) complexes on changing the denticity of the blocking ligands

S Roy, PK Bhaumik, K Harms, S Chattopadhyay - Polyhedron, 2014 - Elsevier
Abstract Three cadmium (II) complexes,[Cd (dmpn)(μ-1, 1-N 3) 2] n (1),[Cd (L 1) 2 Cd (N 3)
2](2) and [Cd 2 (L 2) 2 (Cl) 2](3){where dmpn is a bidentate chelating ligand N, N-dimethyl-1 …

Three d10 metal coordination compounds based on pyrazole-3-carboxylic acid showing mixed-ligand characteristic: Syntheses, crystal structures, and …

GN Liu, WJ Zhu, YN Chu, C Li - Inorganica Chimica Acta, 2015 - Elsevier
Solvothermal reaction of pyrazole-3-carboxylic acid (H 2 pac) and different d 10 metal salt
with or without auxiliary organic ligand afforded three new coordination compounds:[Cd …

One-pot synthesis, crystal structure and theoretical calculations of a dinuclear Mn (III) complex with in-situ generated O, N, O-and O, N-donor dichelating hydrazone …

E Pousaneh, S Sadighian, R Bikas… - Journal of Molecular …, 2020 - Elsevier
A new dinuclear Mn (III) complex,[Mn 2 (L) 2 (CH 3 OH) 2](1), was synthesized by one-pot
reaction of 2-aminobenzoylhydrazide, salicylaldehyde and Mn (OAc) 2· 4H 2 O in methanol …

A comparative investigation on the surface and physicochemical properties of organobimetallic thiocyanate complexes of Cadmium, Zinc, Mercury and Manganese

S Cynthia, S Muthupandi, G Ramalingam… - Zeitschrift für …, 2024 - degruyter.com
The single crystals of bimetallic thiocyanate ligands, namely manganese cadmium
thiocyanate (MCTC), zinc cadmium thiocyanate (ZCTC), manganese mercury thiocyanate …

外源亚精胺对镉胁迫下黑麦草的生理调控效应.

余志强, 胡嘉源, 李尚珂, 施维林… - Asian Journals of …, 2023 - search.ebscohost.com
外源亚精胺对镉胁迫下黑麦草的生理调控效应 Page 1 生态毒理学报 Asian Journal of
Ecotoxicology 第18 卷第5 期2023 年10 月 Vol. 18, No.5 Oct. 2023 基金项目:国家自然科学基金 …