Dual reactivity based dynamic covalent chemistry: mechanisms and applications

L You - Chemical Communications, 2023 - pubs.rsc.org
Dynamic covalent chemistry (DCC) focuses on the reversible formation, breakage, and
exchange of covalent bonds and assemblies, setting a bridge between irreversible organic …

New Advances in Covalent Network Polymers via Dynamic Covalent Chemistry

Z Lei, H Chen, S Huang, LJ Wayment, Q Xu… - Chemical …, 2024 - ACS Publications
Covalent network polymers, as materials composed of atoms interconnected by covalent
bonds in a continuous network, are known for their thermal and chemical stability. Over the …

Cavity-Shape-Dependent Divergent Chemical Reaction inside Aqueous Pd6L4 Cages

D Chakraborty, S Ali, P Choudhury… - Journal of the …, 2023 - ACS Publications
Chemical reactions inside the confined pockets of enzyme-mimicking hosts, such as cages
and macrocycles, have been an emerging field of interest over the past decade. Although …

Host–Guest Interactions Induced Enhancement in Oxidase-Like Activity of a Benzothiadiazole Dye Inside an Aqueous Pd8L4 Barrel

D Chakraborty, N Kaur, J Sahoo, N Hickey… - Journal of the …, 2024 - ACS Publications
The effect of host–guest interactions on the chemistry of encapsulated molecules is a
fascinating field of research that has gained momentum in recent years. Much of the work in …

Spontaneous and Selective Macrocyclization in Nitroaldol Reaction Systems

Y Qi, M Ayinla, S Clifford… - The Journal of Organic …, 2023 - ACS Publications
Through a dynamic polymerization and self-sorting process, a range of lowellane
macrocycles have been efficiently generated in nitroaldol systems composed of aromatic …

Utilizing Secondary Bonds Formed by Halogen Substituents: Achieving the Dynamic Transition of Low-Bandgap Semiconductor Polymers from Macromolecules to …

X Li, N Tuo, HW Zhang, Y Zhang, WK Dong - Macromolecules, 2024 - ACS Publications
Utilizing supramolecular assembly frameworks as soft materials to investigate the
dissolution-recrystallization dynamics presents a viable approach for converting Cu (II) …

Uncovering tetrazoles as building blocks for constructing discrete and polymeric assemblies

S Dey, M Aggarwal, D Chakraborty… - Chemical …, 2024 - pubs.rsc.org
Metal–organic self-assembly with flexible moieties is a budding field of research due to the
possibility of the formation of unique architectures. Tetrazole, characterised by four nitrogen …

Lignin-based vitrimer containing dynamic borate ester bonds with intrinsic photoconversion and excellent photothermal remoldability

L Du, T Wang, S Luo, Z Liu, B Wang, Y Ma… - International Journal of …, 2024 - Elsevier
The development of photoresponsive shape memory materials based on the photothermal
conversion properties of lignin and the low activation energy of the dynamic covalent borate …

Effects of additional ring-fusion site on dual reactivity based dynamic covalent chemistry

F Zhong, X Wan, L You - Tetrahedron, 2024 - Elsevier
Tautomers are widespread in organic chemistry, and their unique reactivity allows diverse
transformations. In this work, the incorporation of nearby amide ring-fusion site offered a …

Predisposition in Dynamic Covalent Chemistry: The Role of Non‐Covalent Interactions in the Assembly of Tetrahedral Boronate Cages

M Rondelli, J Pasán, I Fernández… - Chemistry–A European …, 2024 - Wiley Online Library
Directional bonding strategies guide the design of complex molecular architectures, yet
challenges arise due to emergent behavior. Rigid structures face geometric constraints and …