From time to time reactions involving both transient and persistent radical intermediates
were discovered that lead to a highly dominant and unusually selective formation of the …

Providing a comprehensive review of reactions of oxidation for different classes of organic
compounds and polymers, and biological processes mediated by free radicals, Oxidation …

The necessity of sustainable development in the chemical industry has continuously drawn
attention to find safe, environmentally friendly and atom-economic chemical processes …

This review covers fundamental kinetic features of living radical polymerization (LRP).
Theories on polymerization rate Rp and polydispersity index (PDI) and experimental …

1.2 Background Radical polymerization is of enormous industrial importance; approximately
50% of all commercial polymers are produced by radical polymerization.(23) The process is …

The production of a range of acrylate and acrylamide polymers in completely open reaction
vessels has been achieved utilizing the PET-RAFT polymerization technique with zinc …

Trialkylhydroxylamines and persistent nitroxide radicals are important regulators of living
radical polymerizations. Since the polymerization times decrease with increasing rate of the …

The activation and deactivation rate constants in atom transfer radical polymerization
(ATRP) were measured using model compounds. The activation rate constants were …

Absolute rate constants for the cross-coupling reaction of several carbon-centered radicals
with various nitroxides and their temperature dependence have been determined in liquids …

The synthesis of various new trialkylhydroxylamines is described. The rate constant of the
C− O bond cleavage of these new alkoxyamines has been measured. For example, C− O …