Recent advances in formic acid electro-oxidation: From the fundamental mechanism to electrocatalysts

Z Fang, W Chen - Nanoscale Advances, 2021 - pubs.rsc.org
Direct formic acid fuel cells have attracted significant attention because of their low fuel
crossover, high safety, and high theoretical power density among all the proton-exchange …

Understanding formic acid oxidation mechanism on platinum single crystal electrodes

E Herrero, JM Feliu - Current Opinion in Electrochemistry, 2018 - Elsevier
Recent results on the formic acid oxidation reaction on platinum electrodes, especially those
obtained for platinum single crystal electrodes are reviewed. With all the available data, a …

Tailoring the antipoisoning performance of Pd for formic acid electrooxidation via an ordered PdBi intermetallic

T Shen, S Chen, R Zeng, M Gong, T Zhao, Y Lu… - ACS …, 2020 - ACS Publications
Pd-based materials are promising electrocatalysts for the formic acid oxidation reaction
(FAOR) but suffer from poor durability due to the poisoning of adsorbed carbon monoxide …

Development of a High-Performance Ammonium Formate Fuel Cell

Z Pan, Z Zhang, W Li, X Huo, Y Liu, OC Esan… - ACS Energy …, 2023 - ACS Publications
Direct formate fuel cells are attractive due to their high theoretical voltage of 1.45 V, facile
and complete formate oxidation in alkaline media, and ease of handling during storage and …

Shape reconstruction from commercial Pt/C to high-index Pt/C for advanced electrocatalysts

L Ji, M Lin, W Yan, Y Cai, G Li, J Zheng, S Zhou… - ACS …, 2023 - ACS Publications
Pt-based materials with high-index facets (HIFs) are highly regarded as efficient
electrocatalysts, because of their abundant active step sites. Nevertheless, it is still a …

Recent progress of palladium-based electrocatalysts for the formic acid oxidation reaction

T Shen, J Zhang, K Chen, S Deng, D Wang - Energy & Fuels, 2020 - ACS Publications
Direct formic acid fuel cells (DFAFCs) are considered as one of the promising energy
conversion devices. In recent years, Pd-based nanomaterials have attracted widespread …

Unravelling the complex causality behind Fe–N–C degradation in fuel cells

G Bae, MM Kim, MH Han, J Cho, DH Kim… - Nature Catalysis, 2023 - nature.com
Beyond great advances in initial activity, Fe–N–C catalysts face the next challenge of
stability issue in acidic medium that must be overcome to replace Pt in fuel cell cathode …

pH effects in a model electrocatalytic reaction disentangled

X Zhu, J Huang, M Eikerling - JACS Au, 2023 - ACS Publications
Varying the solution pH not only changes the reactant concentrations in bulk solution but
also the local reaction environment (LRE) that is shaped furthermore by macroscopic mass …

Atomic Ordering Effect of Intermetallic PdCoNi/rGO Catalysts on Formic Acid Electro-oxidation

S Hu, Z Gao, S Gao, J Wang… - ACS Applied Energy …, 2023 - ACS Publications
Pd-based alloys, especially for alloys containing early transition metals, have been
extensively designed and applied to electro-oxidize formic acid for direct formic acid fuel …

Pd–Au nanostructured electrocatalysts with tunable compositions for formic acid oxidation

E Plaza-Mayoral, IJ Pereira… - ACS Applied Energy …, 2022 - ACS Publications
Green transition requires strategies to develop active and stable nanomaterials for energy
conversion. We describe the preparation of Pd–Au bimetallic nanocatalysts using a …