Substituent Effect of Styryl Monomers on Composition and Property Enhancement of Dicyclopentadiene-Based Cycloolefin Copolymers

S Dong, X Duan, T Nan, C Lin, B Liu, D Cui - Macromolecules, 2023 - ACS Publications
Cyclic olefin copolymers based on dicyclopentadiene (DCPD) are very attractive due to the
readily available DCPD resource, where the dangling C= C bonds are reactive and facilitate …

Closing the Loop of Cyclopolymerization of Nonconjugated α, ω-Diolefin Diasteroselectivity and α-Olefin Polymerization Enantioselectivity

O D'Anania, F De Stefano, C De Rosa, G Talarico… - ACS …, 2024 - ACS Publications
The cyclopolymerization of α, ω-dienes catalyzed by transition metals (TMs) is one of the
most attractive synthetic routes for the production of cyclic polyolefins (COPs). These COPs …

The preparation of polyolefin elastomer functionalized with polysiloxane and its effect in ethylene-propylene-diene monomer/silicon rubber blends

Y Cai, J Zheng, Y Hu, J Wei, H Fan - European Polymer Journal, 2022 - Elsevier
The functionalization of polyolefin elastomer with polysiloxane can prepare novel elastomer
with great compatibility, antifouling property, thermal stability and dielectricity. Herein …

Dynamically cross-linked polyolefins via hydrogen bonds: Tough yet soft thermoplastic elastomers with high elastic recovery

G Leone, B Palucci, G Zanchin, A Vignali… - ACS Applied Polymer …, 2022 - ACS Publications
The fabrication of polyolefin thermoplastic elastomers (P-TPEs) with superior robustness
(high strength and high toughness) is challenging. Integrating dynamic (reversible) …

α, ω-Diene Generation from Ethylene and Butadiene by Copolymer Upcycling

MA Bruening, S Xiong, T Agapie - ACS Sustainable Chemistry & …, 2023 - ACS Publications
Linear α-olefins are accessed efficiently from ethylene in the Shell higher olefin process
(SHOP), an industrial process practiced on a million-ton scale that generates a statistical …

Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers

J Nie, F Ren, Z Li, K Tian, H Zou, X Hou - Polymer Chemistry, 2022 - pubs.rsc.org
Several binuclear vanadium complexes were synthesized and investigated as catalysts for
ethylene (co) polymerization. Under the activation of Et2AlCl, the binuclear vanadium …

Chemical upcycling of polybutadiene into size controlled α, ω-dienes and diesters via sequential hydrogenation and cross-metathesis

C Vos, I Beckers, G O'Rourke, D De Vos - Chemical Science, 2025 - pubs.rsc.org
Plastic waste conversion into valuable chemicals is a promising alternative to landfill or
incineration. In particular, the chemical upcycling of polybutadiene rubber (PBR) could …

Functionalized cyclic olefin copolymers: chemoselective polymerization of a cyclopropane-containing norbornadiene dimer using a titanium catalyst and post …

Y Iwata, T Shiono, S Matsuoka - Polymer Chemistry, 2025 - pubs.rsc.org
The synthesis of functionalized polyolefins is important for tuning their properties and
expanding their application range. However, the copolymerization of olefins with polar …

Synthesis, characterization and ethylene (Co) polymerization of binuclear Vanadium (IV) catalysts based on xanthene-bridged bis-salicylaldiminato ligands

S Ren, X Xiao, P Huang, M Zhou, T Li, Q You… - European Polymer …, 2024 - Elsevier
Bimetallic complexes have attracted much attention due to their excellent catalytic
performances in many fields. Herein six xanthene-bridged bis-salicylaldiminato [ON] …

Copolymerization of tricyclopentadiene and ethylene catalyzed by thiophene-fused-heterocyclic cyclopentadienyl scandium complexes

L Huang, S Zhang, C Wu, P He, B Wang - Polymer Chemistry, 2024 - pubs.rsc.org
Cyclic olefin copolymers (COCs) are excellent optical materials, and are of fundamental
interest and practical importance. Bulky cyclic olefin based COCs possess higher glass …