Nanoconfined ionic liquids

S Zhang, J Zhang, Y Zhang, Y Deng - Chemical Reviews, 2017 - ACS Publications
Ionic liquids (ILs) have been widely investigated as novel solvents, electrolytes, and soft
functional materials. Nevertheless, the widespread applications of ILs in most cases have …

Reusable N-heterocyclic carbene complex catalysts and beyond: a perspective on recycling strategies

W Wang, L Cui, P Sun, L Shi, C Yue, F Li - Chemical reviews, 2018 - ACS Publications
With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past
decade, NHC metal complexes have gained wide applications in the research field of …

Immobilization of molecular catalysts in supported ionic liquid phases

C Van Doorslaer, J Wahlen, P Mertens… - Dalton …, 2010 - pubs.rsc.org
In a supported ionic liquid phase (SILP) catalyst system, an ionic liquid (IL) film is
immobilized on a high-surface area porous solid and a homogeneous catalyst is dissolved …

Fifteen years of supported ionic liquid phase-catalyzed hydroformylation: material and process developments

JM Marinkovic, A Riisager, R Franke… - Industrial & …, 2018 - ACS Publications
This review describes the development of supported ionic liquid phase (SILP) materials as
novel hydroformylation catalysts. Ligand-modified rhodium catalysts can be immobilized in a …

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

J Dupont, BC Leal, P Lozano, AL Monteiro… - Chemical …, 2024 - ACS Publications
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

Current state of the art of the solid Rh-based catalyzed hydroformylation of short-chain olefins

S Hanf, L Alvarado Rupflin, R Gläser, SA Schunk - Catalysts, 2020 - mdpi.com
The hydroformylation of olefins is one of the most important homogeneously catalyzed
processes in industry to produce bulk chemicals. Despite the high catalytic activities and …

Rhodium–Phosphite SILP Catalysis for the Highly Selective Hydroformylation of Mixed C4 Feedstocks

M Jakuttis, A Schönweiz, S Werner… - Angewandte Chemie …, 2011 - Wiley Online Library
The hydroformylation of alkenes catalyzed by dissolved rhodium complexes is not only one
of the largest applications of homogeneous catalysis in industry,[1] but also an established …

Microkinetic Modeling of the Transient CO2 Methanation with DFT‐Based Uncertainties in a Berty Reactor

B Kreitz, GD Wehinger, CF Goldsmith… - ChemCatChem, 2022 - Wiley Online Library
The transient operation of methanation reactors can become desirable when coupled with
fluctuating renewable energies in Power‐to‐Gas scenarios, which requires suitable kinetic …

Immobilized catalysts for hydroformylation reactions: A versatile tool for aldehyde synthesis

ÂCB Neves, MJF Calvete… - European Journal of …, 2012 - Wiley Online Library
Olefin hydroformylation is a widely used process, both on large scales and in fine chemistry,
with catalyst reuse still being one of the main objectives. In recent years, developments in …

Recycling homogeneous catalysts simply by organic solvent nanofiltration: new ways to efficient catalysis

JM Dreimann, M Skiborowski, A Behr… - ChemCatChem, 2016 - Wiley Online Library
Organic solvent nanofiltration is a convenient method for the recovery of homogeneous
transition metal catalysts. The long chain olefin 1‐dodecene is hydroformylated …