Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

Z Chen, Y Jiang, L Zhang, Y Guo… - Journal of the American …, 2019 - ACS Publications
A robust and practical protocol for preparing alkyl aryl ethers has been developed, which
relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero) aryl …

Light‐Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by a NiII‐Aryl Complex

L Yang, HH Lu, CH Lai, G Li, W Zhang… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract A highly effective C− O coupling reaction of (hetero) aryl electrophiles with primary
and secondary alcohols is reported. Catalyzed by a NiII‐aryl complex under long‐wave UV …

Arylation with unsymmetrical diaryliodonium salts: a chemoselectivity study

J Malmgren, S Santoro, N Jalalian… - … A European Journal, 2013 - Wiley Online Library
Phenols, anilines, and malonates have been arylated under metal‐free conditions with
twelve aryl (phenyl) iodonium salts in a systematic chemoselectivity study. A new “anti‐ortho …

Chemoselective, Scalable Nickel‐Electrocatalytic O‐Arylation of Alcohols

HJ Zhang, L Chen, MS Oderinde… - Angewandte …, 2021 - Wiley Online Library
The formation of aryl‐alkyl ether bonds through cross coupling of alcohols with aryl halides
represents a useful strategic departure from classical SN2 methods. Numerous tactics …

Recent advances in the transition metal catalyzed etherification reactions

KK Krishnan, SM Ujwaldev, KS Sindhu, G Anilkumar - Tetrahedron, 2016 - Elsevier
The C single bond O bond-forming reactions are important in organic synthesis due to the
presence of these bonds in numerous natural products, biologically important compounds …

A general and efficient catalyst for palladium-catalyzed C− O coupling reactions of aryl halides with primary alcohols

S Gowrisankar, AG Sergeev, P Anbarasan… - Journal of the …, 2010 - ACS Publications
An efficient procedure for palladium-catalyzed coupling reactions of (hetero) aryl bromides
and chlorides with primary aliphatic alcohols has been developed. Key to the success is the …

A Single Phosphine Ligand Allows Palladium‐Catalyzed Intermolecular C O Bond Formation with Secondary and Primary Alcohols

X Wu, BP Fors, SL Buchwald - … Chemie International Edition, 2011 - Wiley Online Library
Aryl alkyl ethers are present in many naturally occurring and medicinally relevant
compounds.[1] Copper [2]-and palladiumcatalyzed CÀO bond-forming reactions have …

Decarboxylative etherification of aromatic carboxylic acids

S Bhadra, WI Dzik, LJ Goossen - Journal of the American …, 2012 - ACS Publications
Decarboxylative Chan–Evans–Lam-type couplings are presented as a new strategy for the
regiospecific construction of diaryl and alkyl aryl ethers starting from easily available …

Cu-catalyzed one-pot synthesis of unsymmetrical diaryl thioethers by coupling of aryl halides using a thiol precursor

DJC Prasad, G Sekar - organic letters, 2011 - ACS Publications
An efficient Cu-catalyzed one-pot approach for the synthesis of unsymmetrical diaryl
thioethers using potassium ethyl xanthogenate as a thiol surrogate is developed. This new …