Chiral Self-sorting in Cage-like Compounds

C Li, Y Zuo, YQ Zhao, S Zhang - Chemistry Letters, 2020 - academic.oup.com
Chiral self-sorting in cage-like compounds is drawing increasing attention in recent years. It
is of great importance in controlling the chirality of the formed cages and their chirality …

Theoretical and computational methodologies for understanding coordination self-assembly complexes

S Takahashi, S Iuchi, S Hiraoka, H Sato - Physical Chemistry Chemical …, 2023 - pubs.rsc.org
This perspective highlights three theoretical and computational methods to capture the
coordination self-assembly processes at the molecular level: quantum chemical modeling …

Structure-switching M 3 L 2 Ir (III) coordination cages with photo-isomerising azo-aromatic linkers

S Oldknow, DR Martir, VE Pritchard, MA Blitz… - Chemical …, 2018 - pubs.rsc.org
Cyclotriguaiacylene has been functionalised with 3-or 4-pyridyl-azo-phenyl groups to form a
series of molecular hosts with three azobenzene-type groups that exhibit reversible photo …

Navigated Self-Assembly of a Pd2L4 Cage by Modulation of an Energy Landscape under Kinetic Control

T Tateishi, S Takahashi, A Okazawa… - Journal of the …, 2019 - ACS Publications
Kinetic control of molecular self-assembly remains difficult because of insufficient
understanding of molecular self-assembly mechanisms. Here we report the formation of a …

Solvent-Directed Social Chiral Self-Sorting in Pd2L4 Coordination Cages

A Walther, G Tusha, B Schmidt… - Journal of the …, 2024 - ACS Publications
A family of Pd2 L 4 cages prepared from ligands based on an axially chiral diamino-[1, 1′-
biazulene] motif (serving as a unique azulene-based surrogate of the ubiquitous BINOL …

Squarate-Tethered Enantiomeric Imido-Pd (II) Cages for Recognition and Separation of Chiral Organic Molecules

C Jose, M Sarkar, P Rajasekar, T Tewari… - Inorganic …, 2023 - ACS Publications
Chiral coordination cages have emerged as an efficient platform for enantioselective
processes via host–guest interactions. Here, we report an enantiomeric pair of tetrahedral …

Probing the dynamics of the imine-based pentafoil knot and pentameric circular helicate assembly

JF Ayme, JE Beves, CJ Campbell… - Journal of the American …, 2019 - ACS Publications
We investigate the self-assembly dynamics of an imine-based pentafoil knot and related
pentameric circular helicates, each derived from a common bis (formylpyridine) bipyridyl …

Self‐Assembly Processes of Pd (II)‐and Pt (II)‐Linked Discrete Self‐Assemblies Revealed by QASAP

S Hiraoka - Israel Journal of Chemistry, 2019 - Wiley Online Library
Recent progress in the understanding of discrete coordination self‐assembly processes is
summarized. Aiming to make the problems in the investigation of molecular self‐assembly …

Cyclotriveratrylene (CTV): Rise of an untapped supramolecular prodigy providing a new generation of sensors

N Patel, K Modi, K Bhatt, B Mohan, J Parikh… - Journal of Molecular …, 2023 - Elsevier
The problem of global environmental contamination is a result of rapid industrialisation.
Untreated industrial waste releases hazardous metal ions into the air and water, which when …

Fundamental Cause of Bio-Chirality: Space-Time Symmetry—Concept Review

VV Dyakin - Symmetry, 2022 - mdpi.com
The search for fundamental determinants of bio-molecular chirality is a hot topic in biology,
clarifying the meaning of evolution and the enigma of life's origin. The question of origin may …