1, 2, 3-Triazole and its analogues: new surrogates for diazo compounds

M Akter, K Rupa, P Anbarasan - Chemical Reviews, 2022 - ACS Publications
Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts

D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Reactions of metallocarbenes derived from N-sulfonyl-1, 2, 3-triazoles

HML Davies, JS Alford - Chemical Society Reviews, 2014 - pubs.rsc.org
Metal-stabilized carbenes derived from diazo compounds have become broadly useful
reactive intermediates for organic synthesis. This tutorial review will describe the recent …

New approaches to the synthesis of metal carbenes

M Jia, S Ma - Angewandte Chemie International Edition, 2016 - Wiley Online Library
Metal carbenes usually possess versatile reactivities that are controlled by the presence of
both the metals and the ligands. Diazo compounds are commonly used for the generation of …

Copper‐catalyzed enantioselective doyle–kirmse reaction of azide‐ynamides via α‐imino copper carbenes

X Liu, LG Liu, CM Chen, X Li, Z Xu, X Lu… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract [2, 3]‐Sigmatropic rearrangement reaction involving sulfonium ylide (Doyle–Kirmse
reaction) generated from metal carbenes represents one of the powerful methods for the …

Recent advances in transition-metal-catalyzed denitrogenative transformations of 1, 2, 3-triazoles and related compounds

P Anbarasan, D Yadagiri, S Rajasekar - Synthesis, 2014 - thieme-connect.com
Suitably substituted electron-deficient 1, 2, 3-triazoles exist in equilibrium with their ring-
opened α-diazoimine tautomers. This phenomenon was used to facilitate the generation of …

Sulfur-based ylides in transition-metal-catalysed processes

JD Neuhaus, R Oost, J Merad, N Maulide - Sulfur Chemistry, 2019 - Springer
Traditionally employed in the synthesis of small ring systems and rearrangement chemistry,
sulfur-based ylides occupy a unique position in the toolbox of the synthetic organic chemist …

Transition metal-catalyzed [2, 3]-sigmatropic rearrangements of ylides: An update of the most recent advances

Z Sheng, Z Zhang, C Chu, Y Zhang, J Wang - Tetrahedron, 2017 - Elsevier
Abstract [2, 3]-sigmatropic rearrangements of ylides are useful methods for synthesizing
functional molecules, especially for these containing heteroatoms. This short report focuses …

Ru(II)-Catalyzed [1,4]-Sigmatropic Rearrangement and Intramolecular Concerted SNAr of Aryl and Heteroarylthio Derivatives using Quinoid Carbene

S Pan, MS Sk, B Sanyal, L Roy, R Samanta - ACS Catalysis, 2024 - ACS Publications
A Ru (II)-catalyzed straightforward and efficient strategy has been developed to construct O-
alkylated arylnaphthyl thioether derivatives using arylthioacetates/arylalkylthioethers with …

[图书][B] Sulfur chemistry

X Jiang - 2019 - books.google.com
Page 1 Topics in Current Chemistry Collections Xuefeng Jiang Editor Sulfur Chemistry Page 2
Topics in Current Chemistry Collections Journal Editors Massimo Olivucci, Siena, Italy and …