Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Energetic materials include explosives, propellants, and pyrotechnics that are used for a
variety of military purposes and civilian applications. 1Ā3 An explosive is defined as a …

The terminal uranium nitride linkage is a fundamental target in the study of f-orbital
participation in metal-ligand multiple bonding but has previously eluded characterization in …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

The forefront of research into the complexes of uranium reveals chemical transformations
that challenge and expand our view of this unique element. Certain ligands form multiple …

The nature and extent of covalency in uranium bonding is still unclear compared with that of
transition metals, and there is great interest in studying uranium–ligand multiple bonds …

There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …

Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …

Dinitrogen cleavage provides an attractive but poorly studied route to the assembly of
multimetallic nitride clusters. Here, we show that the monoelectron reduction of the …

Abstract Uranium nitride [U≡ N] x is an alternative nuclear fuel that has great potential in the
expanding future of nuclear power; however, very little is known about the U≡ N …