High-voltage positive electrode materials for lithium-ion batteries

W Li, B Song, A Manthiram - Chemical Society Reviews, 2017 - pubs.rsc.org
The ever-growing demand for advanced rechargeable lithium-ion batteries in portable
electronics and electric vehicles has spurred intensive research efforts over the past decade …

Nickel‐rich and lithium‐rich layered oxide cathodes: progress and perspectives

A Manthiram, JC Knight, ST Myung… - Advanced Energy …, 2016 - Wiley Online Library
Ni‐rich layered oxides and Li‐rich layered oxides are topics of much research interest as
cathodes for Li‐ion batteries due to their low cost and higher discharge capacities compared …

First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk

RA House, GJ Rees, MA Pérez-Osorio, JJ Marie… - Nature Energy, 2020 - nature.com
Li-rich cathode materials are potential candidates for next-generation Li-ion batteries.
However, they exhibit a large voltage hysteresis on the first charge/discharge cycle, which …

Hysteresis‐suppressed reversible oxygen‐redox cathodes for sodium‐ion batteries

N Voronina, MY Shin, HJ Kim, N Yaqoob… - Advanced Energy …, 2022 - Wiley Online Library
Oxygen‐redox‐based cathode materials for sodium‐ion batteries (SIBs) have attracted
considerable attention in recent years owing to the possibility of delivering additional …

Insights into Li‐rich Mn‐based cathode materials with high capacity: from dimension to lattice to atom

SL Cui, MY Gao, GR Li, XP Gao - Advanced Energy Materials, 2022 - Wiley Online Library
Li‐rich Mn‐based layered oxides are regarded as the most promising cathode materials for
advanced lithium‐ion batteries with energy density as high as 400 Wh kg− 1. However …

[HTML][HTML] Reversible anionic redox chemistry in layered Li4/7 [□ 1/7Mn6/7] O2 enabled by stable Li–O-vacancy configuration

X Cao, H Li, Y Qiao, P He, Y Qian, X Yue, M Jia… - Joule, 2022 - cell.com
The combination of anionic and cationic activities within Li-rich materials breaks through the
traditional capacity limitation and achieves high-energy-density batteries. However, the …

Lithium‐and manganese‐rich oxide cathode materials for high‐energy lithium ion batteries

J Wang, X He, E Paillard, N Laszczynski… - Advanced energy …, 2016 - Wiley Online Library
Layered lithium‐and manganese‐rich oxides (LMROs), described as xLi2MnO3·(1–x)
LiMO2 or Li1+ yM1–yO2 (M= Mn, Ni, Co, etc., 0< x< 1, 0< y≤ 0.33), have attracted much …

Lithium Extraction Mechanism in Li-Rich Li2MnO3 Involving Oxygen Hole Formation and Dimerization

H Chen, MS Islam - Chemistry of Materials, 2016 - ACS Publications
Lithium-rich oxide electrodes with layered structures have attracted considerable interest
because they can deliver high energy densities for lithium-ion batteries. However, there is …

Quantifying the Capacity Contributions during Activation of Li2MnO3

J Rana, JK Papp, Z Lebens-Higgins, M Zuba… - ACS Energy …, 2020 - ACS Publications
Though Li2MnO3 was originally considered to be electrochemically inert, its observed
activation has spawned a new class of Li-rich layered compounds that deliver capacities …

Review of the US Department of Energy's “deep dive” effort to understand voltage fade in Li-and Mn-rich cathodes

JR Croy, M Balasubramanian… - Accounts of chemical …, 2015 - ACS Publications
Conspectus The commercial introduction of the lithium-ion (Li-ion) battery nearly 25 years
ago marked a technological turning point. Portable electronics, dependent on energy …