Electrocatalytic hydrogenation of biomass-derived organics: a review

SA Akhade, N Singh, OY Gutiérrez… - Chemical …, 2020 - ACS Publications
Sustainable energy generation calls for a shift away from centralized, high-temperature,
energy-intensive processes to decentralized, low-temperature conversions that can be …

Controlling the surface environment of heterogeneous catalysts using self-assembled monolayers

CA Schoenbaum, DK Schwartz… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Rationally designing and producing suitable catalysts to promote specific
reaction pathways remains a major objective in heterogeneous catalysis. One approach …

Bifunctional catalysts for upgrading of biomass-derived oxygenates: a review

AM Robinson, JE Hensley, JW Medlin - ACS catalysis, 2016 - ACS Publications
Deoxygenation is an important reaction in the conversion of biomass-derived oxygenates to
fuels and chemicals. A key route for biomass refining involves the production of pyrolysis oil …

Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium

G Cheng, A Jentys, OY Gutiérrez, Y Liu, YH Chin… - Nature Catalysis, 2021 - nature.com
Solvents not only disperse reactants to enhance mass transport in catalytic reactions but
also alter the reaction kinetically. Here, we show that the rate of benzaldehyde …

Elucidating acidic electro-oxidation pathways of furfural on platinum

AM Román, JC Hasse, JW Medlin, A Holewinski - ACS catalysis, 2019 - ACS Publications
Electrocatalysis poses a number of possible advantages for the valorization of biomass-
derived feedstocks, most critically its amenability to direct conversion in acidic aqueous …

Directing reaction pathways by catalyst active-site selection using self-assembled monolayers

SH Pang, CA Schoenbaum, DK Schwartz… - Nature …, 2013 - nature.com
One key route for controlling reaction selectivity in heterogeneous catalysis is to prepare
catalysts that exhibit only specific types of sites required for desired product formation. Here …

Electroreductive C–C coupling of furfural and benzaldehyde on Cu and Pb surfaces

J Anibal, B Xu - ACS Catalysis, 2020 - ACS Publications
Biomass derived species represent an emerging alternative to petroleum as an industrial
carbon feedstock. Effective utilization of biomass requires reductive upgrading of the raw …

Importance of interface open circuit potential on aqueous hydrogenolytic reduction of benzyl alcohol over Pd/C

G Cheng, W Zhang, A Jentys, EE Ember… - Nature …, 2022 - nature.com
The open circuit potential (OCP) established by the quasi-equilibrated electrode reaction of
H2 and H3O+ (hydr.), complicates catalytic reactions significantly. The hydrogenolysis rate …

Enhanced Hydrodeoxygenation of m-Cresol over Bimetallic Pt–Mo Catalysts through an Oxophilic Metal-Induced Tautomerization Pathway

A Robinson, GA Ferguson, JR Gallagher, S Cheah… - ACS …, 2016 - ACS Publications
Supported bimetallic catalysts consisting of a noble metal (eg, Pt) and an oxophilic metal
(eg, Mo) have received considerable attention for the hydrodeoxygenation of oxygenated …

High-throughput screening of monometallic catalysts for aqueous-phase hydrogenation of biomass-derived oxygenates

J Lee, Y Xu, GW Huber - Applied Catalysis B: Environmental, 2013 - Elsevier
The initial reaction rates on a per site basis for aqueous-phase hydrogenation (APH) of
different oxygenated compounds: including acetaldehyde, propanal, acetone, xylose …