The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

The mechanochemical, solvent‐free, highly regioselective, rhodium‐catalyzed C− H
methylation of (hetero) arenes is reported. The reaction shows excellent functional‐group …

In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

In the light of the recent potentials of deuterated molecules as pharmaceuticals or even in
mechanistic understanding, efficient methods for their synthesis are continually desired …

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

Comprehensive Summary Sonogashira cross‐coupling protocol, typically showing the
reaction between aryl/vinyl halide and terminal alkyne, has been a widely used protocol for …

The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

In the field of medicinal chemistry, the precise installation of a trideuteromethyl group is
gaining ever‐increasing attention. Site‐selective incorporation of the deuterated “magic …

Whereas there is a significant interest in the rapid construction of diversely substituted
saturated heterocycles, direct and modular access is currently limited to the mono-, 2, 3-, or …