Summary C (sp 3)–H bonds are ubiquitously present in natural raw materials. Direct
functionalization of these bonds provides a highly valuable approach to increasing …

N-Heterocycles can be found in natural products and drug molecules and are indispensable
components in the area of organic synthesis, medicinal chemistry and materials science …

We report a formal (4+ 2) cycloaddition between alkyl-nosylamides and dienes enabled by a
palladium-catalyzed activation of C (sp3)–H bonds beta to the amide group. This atom …

The amide linkage is one of the most important structural moieties in both chemistry and
biology. Here, we briefly discuss recent advances in catalytic intermolecular C–H …

Free or unfunctionalized benzylamines are well known to participate in C–H activation in the
presence of palladium salts. Despite the ease with which these complexes can be activated …

Palladium‐catalyzed cascade cyclization received much attention in organic synthesis due
to its efficiency and rapid transformation of simple starting materials into complex molecular …

Arylated cyclobutanes were accessed by a versatile palladium‐catalyzed secondary C
(sp3)− H activation, exploiting chelation assistance by modular triazoles. The C− H arylation …

Cascade reactions—chemical processes consisting of two or more reactions in one pot—
offer considerable advantages in terms of time, cost, atom efficiency, and reduced waste …

Electron‐deficient propargylic alcohols (EWG= CN, C (O) Ph, CO2Me, C (O) NH2) under
catalyst‐free mild conditions are annulated with Δ1‐pyrrolines to afford functionalized …

In this article, we discuss the recent developments in palladium (Pd)‐catalyzed C (sp3) H
activation assisted by native directing groups. Although studies on preinstalled (exogenous) …