Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Recent advances in luminescent lanthanide based Single-Molecule Magnets

J Long, Y Guari, RAS Ferreira, LD Carlos… - Coordination Chemistry …, 2018 - Elsevier
Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

A Local D4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K**

XL Ding, YQ Zhai, T Han, WP Chen… - … A European Journal, 2021 - Wiley Online Library
Three six‐coordinate DyIII single‐molecule magnets (SMMs)[Dy (OtBu) 2 (L) 4]+ with local
D4h symmetry are obtained by optimizing the equatorial ligands. One of the compounds with …

Ab initio prediction of tunneling relaxation times and effective demagnetization barriers in kramers lanthanide single-molecule magnets

D Aravena - The Journal of Physical Chemistry Letters, 2018 - ACS Publications
Single-molecule magnets (SMMs) are promising candidates for molecule-based quantum
information devices. Their main limitation is their cryogenic operative temperature. To …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

Two Pairs of Homochiral Parallelogram-like Dy4 Cluster Complexes with Strong Magneto-Optical Properties

CM Liu, R Sun, X Hao, BW Wang - Inorganic Chemistry, 2023 - ACS Publications
Two pairs of homochiral Dy (III) tetranuclear cluster complexes derived from (+)/(−)-3-
trifluoroacetyl camphor (D-Htfc/L-Htfc),[Dy4 (OH) 2 (L1) 4 (D-tfc) 2 (DMF) 2]· 4DMF (D …

Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

LR Thomas-Hargreaves, MJ Giansiracusa… - Chemical …, 2021 - pubs.rsc.org
Treatment of the new methanediide–methanide complex [Dy (SCS)(SCSH)(THF)](1Dy,
SCS={C (PPh2S) 2} 2−) with alkali metal alkyls and auxillary ethers produces the bis …

Axial Ligand Field in D4d Coordination Symmetry: Magnetic Relaxation of Dy SMMs Perturbed by Counteranions

J Wu, O Cador, XL Li, L Zhao, B Le Guennic… - Inorganic …, 2017 - ACS Publications
A series of mononuclear DyIII complexes with the general formula [DyLz2 (salicylaldehyde)
2]· X· solvent (Lz= 6-pyridin-2-yl [1, 3, 5] triazine-2, 4-diamine; X= OH–(1· OH), Cl–(2· Cl), Br …

Influence of magnetic interactions and single-ion anisotropy on magnetic relaxation within a family of tetranuclear dysprosium complexes

J Lu, YQ Zhang, XL Li, M Guo, J Wu, L Zhao… - Inorganic …, 2019 - ACS Publications
Six tetranuclear DyIII complexes [Dy4 (L) 2 (CH3OH) 3 (NO3) 3]· 3NO3· 2H2O (1a),[Dy4 (L) 2
(CH3OH) 2 (SCN) 4 (OCH3) 2]· 2CH3OH· 2H2O (1b),{[Dy4 (L) 2 (CH3OH)(SCN) 6 …

Lanthanide molecular nanomagnets as probabilistic bits

GM Gutiérrez-Finol, S Giménez-Santamarina… - npj Computational …, 2023 - nature.com
Over the decades, the spin dynamics of a large set of lanthanide complexes have been
explored. Lanthanide-based molecular nanomagnets are bistable spin systems, generally …