GM Kontogeorgis, A Holster, N Kottaki… - … and Thermal Analysis, 2022 - Elsevier
Water is a fascinating substance with lots of properties not encountered in other compounds. It has been suggested that making use of water's “anomalous” properties can lead to …
The hypothesis that water has a second critical point at deeply supercooled conditions was formulated to provide a thermodynamically consistent interpretation of numerous …
The possible existence of a metastable liquid–liquid transition (LLT) and a corresponding liquid–liquid critical point (LLCP) in supercooled liquid water remains a topic of much …
H Tanaka - The Journal of Chemical Physics, 2020 - pubs.aip.org
Two or more liquid states may exist even for single-component substances, which is known as liquid polymorphism, and the transition between them is called liquid–liquid transition …
For the past 50 years, researchers have sought molecular models that can accurately reproduce water's microscopic structure and thermophysical properties across broad ranges …
R Shi, H Tanaka - Proceedings of the National Academy of …, 2020 - National Acad Sciences
The origin of water's anomalies has been a matter of long-standing debate. A two-state model, dating back to Röntgen, relies on the dynamical coexistence of two types of local …
Empty liquids represent a wide class of materials whose constituents arrange in a random network through reversible bonds. Many key insights on the physical properties of empty …
Z Yu, R Shi, H Tanaka - The Journal of Physical Chemistry B, 2023 - ACS Publications
Water has anomalous thermodynamic and kinetic properties distinct from ordinary liquids. The famous examples are the density maximum at 4° C and the viscosity decrease upon …
It has recently been shown that the TIP4P/Ice model of water can be studied numerically in metastable equilibrium at and below its liquid–liquid critical temperature. We report here …