Intermediates in Mechanochemical Reactions

KJ Ardila‐Fierro, JG Hernández - … Chemie International Edition, 2024 - Wiley Online Library
Mechanochemical reactions offer methodological and environmental advantages for
chemical synthesis, constantly attracting attention within the scientific community. Besides …

Innovations in mechanochemical synthesis: Luminescent materials and their applications

SH Penczner, P Kumar, M Patel, LS Bouchard… - Materials Today …, 2024 - Elsevier
The mechanochemical synthesis (MCS) approach has recently emerged as an eco-friendly
substitute for traditional wet-chemical methods for materials preparation and has many …

Mechanochemical Difluoromethylations of Alcohols

P van Bonn, J Ke, C Weike, JS Ward… - CCS …, 2023 - chinesechemsoc.org
Difluoromethyl ethers are formed through mechanochemical reactions of alcohols with
difluorocarbene in a mixer mill. The protocol could be applied to primary, secondary, and …

Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications

J Fan, Z Yang, S Dai - Green Chemical Engineering, 2024 - Elsevier
Mechanochemistry has been recognized as an efficient and sustainable methodology to
provide a unique driven force and reaction environments under ambient and neat conditions …

The Role of Crystalline Intermediates in Mechanochemical Cyclorhodation Reactions Elucidated by in‐Situ X‐ray Powder Diffraction and Computation

JG Hernández, KJ Ardila‐Fierro… - … A European Journal, 2023 - Wiley Online Library
The occurrence of crystalline intermediates in mechanochemical reactions might be more
widespread than previously assumed. For example, a recent study involving the acetate …

Mechanochemical Synthesis of a Sodium Anion Complex [Na+(2,2,2-cryptand)Na] and Studies of Its Reactivity: Two-Electron and One-Electron Reductions

N Davison, JM Hemingway, C Wills, T Stolar… - Inorganic …, 2024 - ACS Publications
Group 1 metal molecular chemistry is dominated by a+ 1 oxidation state, while a 0 oxidation
state is widespread in the metals. A more exotic, yet still available, oxidation state of group 1 …

Rapid, room-temperature, solvent-free mechanochemical oxidation of elemental gold into organosoluble gold salts

JL Do, T Auvray, CB Lennox, HM Titi, LA Cuccia… - Green …, 2023 - pubs.rsc.org
Gold is highly valued for a wide range of commercial and technological applications but is
processed exclusively through highly aggressive and toxic solvents and/or reagents …

A solvent-free mechanochemical electrophilic C–H thiocyanation of indoles and imidazo [1, 2-a] pyridines using a cost-effective combination of N-chlorosuccinimide …

S Saha, AB Pinheiro, A Chatterjee, ZT Bhutia… - Green …, 2024 - pubs.rsc.org
Herein, we report a solvent-free and sustainable methodology for the electrophilic C–H
thiocyanation of indoles and imidazo [1, 2-a] pyridines in a mixer-mill. A combination of …

Cocrystallization of methyltestosterone with salicylic acid and 2, 2′-disulfanediyldibenzoic acid-Effect on solubility of methyltestosterone and growth of leishmania …

R Fatima, S Yousuf, MI Choudhary - Journal of Molecular Structure, 2024 - Elsevier
Methyltestosterone is a class II anabolic androgenic steroidal drug, structurally resembled to
natural testosterone, produced by body. Two cocrystals of methyltestosterone with …

Calcium Carbide (CaC2) as a C2‐Synthon by Mechanochemistry

A Cortés‐Lobo, JG Hernández - ChemPlusChem, 2024 - Wiley Online Library
Mechanochemical reactions by ball milling have opened new avenues in chemical
synthesis. Particularly, mechanochemistry has facilitated the reaction of insoluble materials …