Geodesic polyarenes by flash vacuum pyrolysis

VM Tsefrikas, LT Scott - Chemical reviews, 2006 - ACS Publications
Geodesic polyarenes constitute a rapidly growing family of polycyclic aromatic hydrocarbons
(PAHs) that resemble the geodesic domes of the great 20th century American architect …

Methods for the chemical synthesis of fullerenes

LT Scott - Angewandte Chemie International Edition, 2004 - Wiley Online Library
C60 has been synthesized by chemical methods in 12 steps. Lessons learned in the
author's laboratory during a decade devoted to the synthesis and study of open geodesic …

A main group metal sandwich: five lithium cations jammed between two corannulene tetraanion decks

AV Zabula, AS Filatov, SN Spisak, AY Rogachev… - Science, 2011 - science.org
Lithium-coordinated polyaromatic anions such as tetrareduced corannulene, C20H104−(1
4−), are useful substrates to model and ultimately improve the graphitic electrodes in lithium …

How charging corannulene with one and two electrons affects its geometry and aggregation with sodium and potassium cations

AV Zabula, SN Spisak, AS Filatov… - … A European Journal, 2012 - Wiley Online Library
Bowl‐shaped mono‐and dianions are prepared by reduction of corannulene (C20H10, 1)
with sodium and potassium metals in the presence of [18] crown‐6 ether. Single‐crystal X …

Tightening of the nanobelt upon multielectron reduction.

AV Zabula, AS Filatov, J Xia, R Jasti… - Angewandte …, 2013 - search.ebscohost.com
Curved polyaromatic hydrocarbons (PAHs) and their charged products are of special
fundamental interest owing to their unique balance of strain and conjugation, which sheds …

[PDF][PDF] Selective endo and exo binding of alkali metals to corannulene

SN Spisak, AV Zabula, AS Filatov… - Angewandte Chemie …, 2011 - academia.edu
The first report of complexation of a transition metal to corannulene in 1997 [1] triggered
intensive exploration of metal binding reactions to bowl-shaped polyaromatic hydrocarbons …

[图书][B] Spectroscopic Properties of Inorganic and Organometallic Compounds: Volume 26

JH Carpenter, SJ Clark, KB Dillon, JD Donaldson… - 2007 - books.google.com
Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique
source of information on an important area of chemistry. Divided into sections mainly …

Synthesis, structures, and physical properties of aromatic molecular-bowl hydrocarbons

YT Wu, JS Siegel - Polyarenes I, 2014 - Springer
This chapter summarizes the synthesis, physical properties, structure, and crystal packing of
buckybowls. Buckybowls exemplify an intermediate class of polynuclear aromatic …

[HTML][HTML] Self-assembly of tetrareduced corannulene with mixed Li–Rb clusters: dynamic transformations, unique structures and record 7 Li NMR shifts

AS Filatov, SN Spisak, AV Zabula, J McNeely… - Chemical …, 2015 - pubs.rsc.org
Self-assembly processes of the highly reduced bowl-shaped corannulene generated by the
chemical reduction with a binary combination of alkali metals, namely Li–Rb, have been …

Reduction of bowl-shaped hydrocarbons: Dianions and tetraanions of annelated corannulenes

I Aprahamian, DV Preda, M Bancu… - The Journal of …, 2006 - ACS Publications
The reduction of several annelated corannulene derivatives was undertaken using lithium
and potassium metals. It was found that annelation affects the annulenic character of …