Applying Classical, Ab Initio, and Machine-Learning Molecular Dynamics Simulations to the Liquid Electrolyte for Rechargeable Batteries

N Yao, X Chen, ZH Fu, Q Zhang - Chemical Reviews, 2022 - ACS Publications
Rechargeable batteries have become indispensable implements in our daily life and are
considered a promising technology to construct sustainable energy systems in the future …

Interphase control for high performance lithium metal batteries using ether aided ionic liquid electrolyte

U Pal, D Rakov, B Lu, B Sayahpour, F Chen… - Energy & …, 2022 - pubs.rsc.org
Future rechargeable Li metal batteries (LMBs) require a rational electrolyte design to
stabilize the interfaces between the electrolyte and both the lithium metal anode and the …

Recent strategies for improving the performance of ionic liquids as battery electrolytes

B Roy, U Pal, M Kar, DR MacFarlane - Current Opinion in Green and …, 2022 - Elsevier
Ionic liquids (ILs) are widely known for their intriguing properties, such as low flammability,
high electrochemical stability, etc., and therefore are considered as promising alternatives to …

Stable and efficient lithium metal anode cycling through understanding the effects of electrolyte composition and electrode preconditioning

D Rakov, M Hasanpoor, A Baskin… - Chemistry of …, 2021 - ACS Publications
Stable metal anode cycling for high energy density batteries can be realized through
modification of electrolyte composition and optimization of formation protocols, ie, electrode …

The impact of electrode conductivity on electrolyte interfacial structuring and its implications on the Na 0/+ electrochemical performance

DA Rakov, J Sun, PV Cherepanov, K Arano… - Energy & …, 2023 - pubs.rsc.org
Molecular and ionic assemblies at electrode/liquid electrolyte interfaces, ie, the electric
double layer (EDL), define battery performance by directing the formation of stable …

High-rate formation protocol enables a high ionic conductivity SEI for sodium-ion batteries

J Sun, IE Gunathilaka, LA O'Dell, PC Howlett… - Journal of Power …, 2023 - Elsevier
The formation process for lithium-ion batteries has been comprehensively investigated,
while the optimization protocols for sodium-ion batteries are barely discussed. The …

Three-in-one fire-retardant poly (phosphate)-based fast ion-conductor for all-solid-state lithium batteries

J Xie, S Qiao, Y Wang, J Sui, L Bao, H Zhou, T Li… - Journal of Energy …, 2023 - Elsevier
The development of flame retardant or nonflammable electrolytes is the key to improve the
safety of lithium batteries, owing to inflammable organic solvents and polymer matrix in …

Polar organic cations at electrified metal with superconcentrated ionic liquid electrolyte and implications for sodium metal batteries

DA Rakov, J Sun, SA Ferdousi, PC Howlett… - ACS Materials …, 2022 - ACS Publications
Understanding the potential-induced changes across the electrode/electrolyte interface, the
so-called electric double layer (EDL), is essential to adjust the working properties of energy …

[HTML][HTML] Investigation of properties and performance of three novel highly concentrated ether-functionalised ionic liquid electrolytes for lithium metal batteries

A Warrington, M Hasanpoor, A Balkis, PC Howlett… - Energy Storage …, 2023 - Elsevier
Abstract Exploring highly concentrated (> 50 mol% Li-salt) ionic liquids as electrolytes for
lithium metal batteries can lead to the development of safer, high-performance batteries with …

Effect of Potential on the Nanostructure Dynamics of Ethylammonium Nitrate at a Graphite Electrode

H Li, J Wang, GG Warr, R Atkin - Small, 2024 - Wiley Online Library
Video‐rate atomic force microscopy (AFM) is used to study the near‐surface nanostructure
dynamics of the ionic liquid ethylammonium nitrate (EAN) at a highly oriented pyrolytic …