Ex-situ generation and synthetic utilization of bare trifluoromethyl anion in flow via rapid biphasic mixing
Fluoroform (CF3H) is the simplest reagent for nucleophilic trifluoromethylation intermediated
by trifluoromethyl anion (CF3–). However, it has been well-known that CF3–should be …
by trifluoromethyl anion (CF3–). However, it has been well-known that CF3–should be …
Facile C− F Bond Activation Approach to FAMT‐Based Difluoromethyl‐BNCT Drug Candidates
A Yokawa, M Hatanaka, K Mikami - Helvetica Chimica Acta, 2021 - Wiley Online Library
Abstract Lithium 1, 3‐bis (2, 6‐diisopropylphenyl)‐1, 3, 2‐diazaborolidinyl‐2‐uide activates
the C− F linkage of fluoroform (CF3H) to provide air‐stable difluoromethylborane …
the C− F linkage of fluoroform (CF3H) to provide air‐stable difluoromethylborane …
Fluoroalkenes from the Defluoroalkylation of Trifluoromethane
Trifluoromethane (HCF3) is a byproduct of fluoropolymer production that has limited
applications. It is often stored or destroyed at the point of production, but if released into the …
applications. It is often stored or destroyed at the point of production, but if released into the …