Phenalenyl radical: Smallest polycyclic odd alternant hydrocarbon present in the graphene sheet

J Ahmed, SK Mandal - Chemical Reviews, 2022 - ACS Publications
Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Solar‐driven production of hydrogen peroxide from water and dioxygen

S Fukuzumi, YM Lee, W Nam - Chemistry–A European Journal, 2018 - Wiley Online Library
Hydrogen peroxide, which is a green oxidant and fuel, is produced by a two‐electron/two‐
proton reduction of dioxygen, two‐electron/two‐proton oxidation of water, or a combination …

Stable olympicenyl radicals and their π-dimers

Q Xiang, J Guo, J Xu, S Ding, Z Li, G Li… - Journal of the …, 2020 - ACS Publications
An olympicenyl radical, a spin 1/2 hydrocarbon radical with C 2 v symmetry and uneven spin
distribution, remains elusive despite the considerable theoretical research interest. Herein …

Amphoteric reactivity of metal–oxygen complexes in oxidation reactions

M Sankaralingam, YM Lee, W Nam… - Coordination Chemistry …, 2018 - Elsevier
Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

Hydrogen peroxide used as a solar fuel in one‐compartment fuel cells

S Fukuzumi, Y Yamada - ChemElectroChem, 2016 - Wiley Online Library
Clean and highly efficient production of solar fuels as well as effective methods to store solar
fuels have long been sought to solve global energy and environmental issues. Among solar …

Exploring closed-shell cationic phenalenyl: From catalysis to spin electronics

A Mukherjee, SC Sau, SK Mandal - Accounts of Chemical …, 2017 - ACS Publications
Conspectus The odd alternant hydrocarbon phenalenyl (PLY) can exist in three different
forms, a closed-shell cation, an open-shell radical, and a closed-shell anion, using its …

Enhancing the performance of paper-based microfluidic fuel cell via optimization of material properties and cell structures: A review

L Li, H Huang, XM Lin, X Fan, Y Sun, W Zhou… - Energy Conversion and …, 2024 - Elsevier
Paper-based microfluidic fuel cell (PMFC) has attracted great attention in the microfluidic
fuel cell field in recent years. It utilizes the spontaneous capillary flow of reactant solutions in …

Redox switching behavior in resistive memory device designed using a solution-processable phenalenyl-based Co (II) complex: experimental and DFT studies

N Kamboj, A Betal, M Majumder, S Sahu… - Inorganic …, 2023 - ACS Publications
We herein report a novel square-planar complex [CoIIL], which was synthesized using the
electronically interesting phenalenyl-derived ligand LH2= 9, 9′-(ethane-1, 2-diylbis …

A flexible on-fiber H2O2 microfluidic fuel cell with high power density

S Wang, D Ye, Z Liu, X Zhu, R Chen, Q Liao… - International Journal of …, 2022 - Elsevier
To promote the simplification and integration of membraneless microfluidic fuel cell (MMFC)
system and combine with flexible portable devices, a flexible on-fiber MMFC exploiting H 2 …

A closed-shell phenalenyl-based dinuclear iron (iii) complex as a robust cathode for a one-compartment H 2 O 2 fuel cell

N Kamboj, A Dey, P Lama, M Majumder… - Dalton …, 2023 - pubs.rsc.org
Closed-shell phenalenyl (PLY) systems are increasingly becoming more attractive as
building blocks for developing promising catalysts and electroactive cathode materials, as …