Metal-catalyzed asymmetric reactions enabled by organic peroxides
N Zhu, H Yao, X Zhang, H Bao - Chemical Society Reviews, 2024 - pubs.rsc.org
As a class of multifunctional reagents, organic peroxides play vital roles in the chemical
industry, pharmaceutical synthesis and polymerization reactions. Metal-catalyzed …
industry, pharmaceutical synthesis and polymerization reactions. Metal-catalyzed …
Chiral Pseudohomogeneous Catalyst Based on Amphiphilic Carbon Quantum Dots for the Enantioselective Kharasch–Sosnovsky Reaction
The term “chiral pseudohomogeneous catalyst (PHC)” denotes a novel concept that
characterizes subnanometric particles exhibiting atomic-level chirality. The PHC based on …
characterizes subnanometric particles exhibiting atomic-level chirality. The PHC based on …
Photoinduced Copper‐Catalyzed Enantioselective Allylic C(sp3)−H Oxidation of Acyclic 1‐Aryl‐2‐alkyl Alkenes as Limiting Substrates
X Chen, HH Li, S Kramer - Angewandte Chemie International …, 2024 - Wiley Online Library
Herein, we disclose a simple copper‐catalyzed method for enantioselective allylic C (sp3)−
H oxidation of unsymmetrical acyclic alkenes, specifically 1‐aryl‐2‐alkyl alkenes. The C− H …
H oxidation of unsymmetrical acyclic alkenes, specifically 1‐aryl‐2‐alkyl alkenes. The C− H …
Chiral amido-oxazoline functionalized MCM-41: A sustainable heterogeneous catalyst for enantioselective Kharasch–Sosnovsky and Henry reactions
N Tavakoli, H Arvinnezhad, S Majidian… - Heliyon, 2024 - cell.com
In this study, a series of chiral amido-oxazoline ligands was synthesized with a primary focus
on immobilizing the most effective ligands on MCM-41 mesoporous material. Following …
on immobilizing the most effective ligands on MCM-41 mesoporous material. Following …
Application of chiral Betti base-copper complexes in enantioselective allylic oxidation of olefins, computational studies of the Betti bases, and docking of the resulting …
Z Sehhat, S Mansoori, H Arvinnezhad, Y Naghdi… - Molecular …, 2023 - Elsevier
Abstract Chiral (R)-and (S)-Betti bases have been initially synthesized from resolution of the
corresponding racemic mixture by diastereomeric recrystallization method using l-(+)-tartaric …
corresponding racemic mixture by diastereomeric recrystallization method using l-(+)-tartaric …
Mechanistic Insights into the Copper‐Catalyzed Cross‐Dehydrogenative Allylic Alkynylation Reaction
P Hünemörder, G Alvarez, L Gräber… - …, 2024 - Wiley Online Library
Allylic functionalization reactions are an important tool for constructing many organic
compounds, as they allow for the insertion of the versatile allyl group. Numerous catalytic …
compounds, as they allow for the insertion of the versatile allyl group. Numerous catalytic …
De novo design and preparation, structural details, and cytotoxic response of a new water soluble (2, 2′–bipy)–(phenylalaninato)–μ–chlorido–copper (II) drug …
F Arjmand, S Khursheed, S Akhter, MF Ansari… - Journal of Molecular …, 2024 - Elsevier
Abstract A new water soluble (2, 2′–bipyridine)–(phenylalaninato)–μ–chlorido–copper (II)
complex was synthesized using ancillary ligands, L-phenylalanine, and 2, 2-bipyridine as a …
complex was synthesized using ancillary ligands, L-phenylalanine, and 2, 2-bipyridine as a …
Copper‐Catalyzed Simultaneous Dehydrogenation and Enantioselective Allylic Oxidation of Alkanes Using Chiral Heterogeneous Ligands to Produce Allylic Esters …
S Majidian, HI Rashid, Y Naghdi… - Applied …, 2024 - Wiley Online Library
ABSTRACT A new asymmetric method for preparing chiral allylic esters from various
unactivated alkanes through simultaneous dehydrogenation and enantioselective allylic …
unactivated alkanes through simultaneous dehydrogenation and enantioselective allylic …
Enhancing catalytic activity of UiO-66 through CuO nanoparticles incorporation: a study on Henry reaction and one-pot allylic CH bond oxidation of olefins
M Mahramasrar, S Rezajo, S Majidian… - Journal of Chemical …, 2024 - Springer
In this work, we prepared CuO NPs@ UiO-66, a zirconium-based metal-organic framework
with a nanoporous structure and high surface area, through a solvothermal method involving …
with a nanoporous structure and high surface area, through a solvothermal method involving …