Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

Nitrous oxide, commonly known as “laughing gas”, is formed as a by-product in several
industrial processes. It is also readily available by thermal decomposition of ammonium …

N-heterocyclic carbenes (NHCs) are recognized for their ability to stabilize various main
group radicals; however, NHC-derived, sulfur-based radicals remain rare. In this study, we …

Over the past decade, numerous stable organic and main‐group radicals have been
synthesized from N‐heterocyclic carbenes (NHCs). The structure of NHCs, in particular …

Stable organic radicals have been of great academic interest not only in the context of
fundamental understanding of reactive intermediates but also because of their numerous …

Persistent and stable nitrogen‐centered organic radicals, including non‐heterocyclic/
heterocyclic nitrogen‐centered radicals and nitrogen‐centered radical complexes, have …

One‐electron reduction of C2‐arylated 1, 3‐imidazoli (ni) um salts (IPrAr) Br (Ar= Ph, 3 a; 4‐
DMP, 3 b; 4‐DMP= 4‐Me2NC6H4) and (SIPrAr) I (Ar= Ph, 4 a; 4‐Tol, 4 b) derived from …

Preparation of novel triarylazoimidazole trichlorogold (III) complexes is described. The new
compounds were characterized using C, H, N elemental analyses, IR, UV/Vis and X-ray …

Developing luminescent radicals with tunable emission is a challenging task due to the
limitation of alternative skeletons. Herein, a series of carbene‐triphenylamine hybrids were …

Notwithstanding the notable progress in the synthesis of N-heterocyclic carbene-stabilized
radicals, aminyl radicals, supported by NHCs or otherwise, have been scarcely studied due …