Looking into the future of hybrid glasses

TD Bennett, S Horike, JC Mauro, MM Smedskjaer… - Nature Chemistry, 2024 - nature.com
Glasses are typically formed by melt-quenching, that is, cooling of a liquid on a timescale
fast enough to avoid ordering to a crystalline state, and formerly thought to comprise three …

Emergence of melt and glass states of halide perovskite semiconductors

A Singh, DB Mitzi - Nature Reviews Materials, 2025 - nature.com
Metal halide perovskites have attracted considerable attention among emerging
semiconductors because they can be fabricated at a low cost and have outstanding …

Local structure in crystalline, glass and melt states of a hybrid metal halide perovskite

A Singh, D Dayton, DM Ladd, G Reuveni… - Journal of the …, 2024 - ACS Publications
The pursuit of structure–property relationships in crystalline metal halide perovskites (MHPs)
has yielded an unprecedented combination of advantageous characteristics for wide …

Rational Design of 2D Metal Halide Perovskites with Low Congruent Melting Temperature and Large Melt-Processable Window

W Wang, CD Liu, CC Fan, XB Fu, CQ Jing… - Journal of the …, 2024 - ACS Publications
Metal halide perovskites (MHPs) have garnered significant attention due to their distinctive
optical and electronic properties, coupled with excellent processability. However, the …

Organic–Inorganic Hybrid Glasses of Atomically Precise Nanoclusters

C Dong, X Song, BE Hasanov, Y Yuan… - Journal of the …, 2024 - ACS Publications
Organic–inorganic atomically precise nanoclusters provide indispensable building blocks
for establishing structure–property links in hybrid condensed matter. However, robust …

Metal Ion-Coordinated Biomolecular Noncovalent Glass with Ceramic-like Mechanics

S Cao, W Fan, R Chang, C Yuan, X Yan - CCS Chemistry, 2024 - chinesechemsoc.org
Glass materials play a vital role in scientific research and engineering applications.
Biomolecular noncovalent glasses (BNG), based on amino acids and peptides, have been …

Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2024 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …

Glass and liquid chemistry of coordination polymers and MOFs

S Horike - Bulletin of the Chemical Society of Japan, 2023 - academic.oup.com
The chemistry of coordination polymers and metal-organic frameworks (MOFs) has
progressed largely with the development of crystallography. The study of “disordered …

Carboxylate-Based Metal–Organic Framework and Coordination Polymer Glasses: Progress and Perspectives

M Kim, Y Lee, HR Moon - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Coordination polymers (CPs) and metal–organic frameworks (MOFs) represent
versatile materials with diverse structural and functional properties, making them appealing …

Creating glassy states of dicarboxylate-bridged coordination polymers

Z Fan, YS Wei, C Das, K Kanamori… - Chemical …, 2023 - pubs.rsc.org
We report the direct formation of dicarboxylate-based coordination polymer glasses through
thermal dehydration. The rearrangement of the coordination networks caused by …