Magnetism Studies of Bis(acyl)phosphide-Supported Eu3+ and Eu2+ Complexes

J Chen, SH Carpenter, TV Fetrow, J Mengell… - Inorganic …, 2022 - ACS Publications
A series of bis (acyl) phosphide-supported Eu complexes were synthesized (bis (acyl)
phosphide= BAP). In this study, BAP ligands proved to be excellent ligands for the synthesis …

New heteronuclear complexes of PdII–LnIII–PdII with Schiff base ligand: Synthesis, crystal structures and chemical properties

D Osypiuk, B Cristovao, L Mazur - Journal of Molecular Structure, 2022 - Elsevier
Starting from the N, N'-bis (2, 3-dihydroxybenzylidene)-1, 3-diaminopropane (H 4 L) the new
cationic complexes with the formulae:[LnPd 2 (H 2 L) 2 (NO 3)](NO 3) Cl· mCH 3 OH· nH 2 O …

3d–4f magnetic exchange interactions and anisotropy in a series of heterobimetallic vanadium (IV)–lanthanide (III) Schiff base complexes

K Kotrle, I Nemec, J Moncol, E Čižmár… - Dalton Transactions, 2021 - pubs.rsc.org
A series of heterobimetallic LnIII–VIV compounds [Ln (VO) L (NO3) 3 (H2O)](Ln= Gd (1), Tb
(2), Dy (3), and Er (4)) assembled by a Schiff base ligand (H2L= N, N′-bis (1-hydroxy-2 …

Structures and magnetic properties of two series of Schiff base binuclear lanthanide complexes

Y Lu, ZM Huang, HH Zou… - Applied Organometallic …, 2023 - Wiley Online Library
Until now, although there are many examples of studying the magnetic properties of Schiff
base binuclear lanthanide complexes, the relationship between the structure and magnetic …

Two-Dimensional Metal Azides Constructed by a Ln@Co6 Cluster and Disordered Co3(N3)11 Units

JY Sun, JP Zhao, FC Liu - Crystal Growth & Design, 2022 - ACS Publications
Two-dimensional metal azides [LnCo9 (Pzc) 6 (OH) 3 (N3) 11· 2 (CH3OH)· 2H2O] n (Ln= Gd
for 1 and Dy for 2) have been solvothermally prepared. In 1 and 2, a heptanuclear Ln@ Co6 …

[HTML][HTML] Metallic core [Ni6IICrIII] as an example of centered heterometallic rings displaying quantum effects

M Antkowiak, B Brzostowski, W Florek… - Journal of Magnetism …, 2022 - Elsevier
The molecular complex containing the bimetallic core Ni 6 Cr representing the centered ring
geometry as well as its frustrated analogue are numerically simulated using the …

Tuning three coordination polymers with dinuclear metal units via pH control: syntheses, structures, and magnetic properties

F Su, S Li, C Han, L Wu, Z Wang - Journal of Solid State Chemistry, 2022 - Elsevier
The self-assembly of three coordination polymers with dinuclear metal units, namely {[Co 2
(bpta)(phen) 2]· 2H 2 O} n (1),{[Co 2 (bpta)(phen)(H 2 O)]· 4H 2 O· CH 3 CN} n (2), and {[Ni 2 …

[HTML][HTML] 镍–稀土单分子磁体的研究进展

李晴燕, 李佳, 刘雨, 胡翔宇, 崔会会, 朱金丽… - Journal of Advances in …, 2024 - hanspub.org
镍(II) 离子具有3d 8 的电子构型. 在八面体场中, 它们倾向于采用高自旋, 表现为顺磁性,
而在正方形平面场中, 它们通常采用低自旋, 表现为抗磁性. 镍(II) 可以与具有f 7-f 11 …

[图书][B] Magnetic Properties and Coordination Polymerization of Lanthanide Phosphate Complexes

JMO Cue - 2021 - search.proquest.com
The intrinsic properties of lanthanides give steric and electronic advantages in rare earth
organometallics. Lanthanides have the potential to accomplish unique applications which …

Simulations of molecular nanomagnets with various metallic cores and topologies

M Antkowiak, B Brzostowski, S Weissman… - ifmpan.poznan.pl
We present the results of simulations of a class of molecular nanomagnets with ring,
centered ring and dimer topologies. We demonstrate [1, 2] that anisotropic Heisenberg …