Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Palladium catalysts have become central to modern organic synthesis, particularly in the
context of cross‐coupling reactions to form C− C and C‐heteroatom bonds. The …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …

The kinetics and mechanism of the base-catalyzed hydrolysis (ArB (OR) 2→ ArB (OH) 2) and
protodeboronation (ArB (OR) 2→ ArH) of a series of boronic esters, encompassing eight …

This report describes the chemoselective coupling of polyfluoroarenes with aryl germanes in
the presence of aromatic C–I, C–Br, C–Cl, C–OTf, and C–SiMe3 groups, as well as …

The Suzuki–Miyaura cross-coupling between polyfluorinated arylboron nucleophiles and
aryl halides enables the efficient construction of polyfluorinated structural motifs frequently …

To simultaneously obtain outstanding stretchability, strength, and charge mobility of
conjugated polymers (CPs) has remained a challenge for the field of stretchable electronics …

We have developed a new dialkylbiaryl monophosphine ligand, GPhos, that supports a
palladium catalyst capable of promoting carbon–nitrogen cross-coupling reactions between …