The diverse functions of isocyanides in phosphorescent metal complexes

GD Sutton, ME Olumba, YH Nguyen, TS Teets - Dalton Transactions, 2021 - pubs.rsc.org
In this Perspective, we highlight many examples of photoluminescent metal complexes
supported by isocyanides, with an emphasis on recent developments including several from …

Controlling the Photophysical Properties of a Series of Isostructural d6 Complexes Based on Cr0, MnI, and FeII

C Wegeberg, D Häussinger, S Kupfer… - Journal of the …, 2024 - ACS Publications
Development of first-row transition metal complexes with similar luminescence and
photoredox properties as widely used RuII polypyridines is attractive because metals from …

Computational aspects to design iridium complexes as emitters for OLEDs

MS Lakshmi, S Mahalakshmi - Molecular Systems Design & …, 2022 - pubs.rsc.org
Organic light-emitting diode (OLED) devices fabricated using iridium complexes have
attracted great attention from researchers for decades due to their high efficiency and opto …

Triplet–Triplet Energy Transfer in Bis-Cyclometalated Iridium Complexes with Pyrene-Substituted Isocyanides

ME Olumba, RM O'Donnell, TN Rohrabaugh Jr… - Inorganic …, 2023 - ACS Publications
Nonlinear optical (NLO) materials are able to modulate responses of electromagnetic
radiation, leading to phenomena critical to modern telecommunications technologies. The …

Solvent-modulated proton-coupled electron transfer in an iridium complex with an ESIPT ligand

S Kim, J Choi, DW Cho, M Ahn, S Eom, J Kim… - Chemical …, 2022 - pubs.rsc.org
Proton-coupled electron transfer (PCET), an essential process in nature with a well-known
example of photosynthesis, has recently been employed in metal complexes to improve the …

Tuning Emission Lifetimes of Ir(C^N)2(acac) Complexes with Oligo(phenyleneethynylene) Groups

R Davidson, YT Hsu, MA Fox, JA Aguilar… - Inorganic …, 2023 - ACS Publications
Emissive compounds with long emission lifetimes (μs to ms) in the visible region are of
interest for a range of applications, from oxygen sensing to cellular imaging. The emission …

Coordination-Driven Self-Assembly of Cyclometalated Iridium Squares Using Linear Aromatic Diisocyanides

ME Olumba, H Na, AE Friedman, TS Teets - Inorganic Chemistry, 2021 - ACS Publications
Here, we demonstrate facile [4+ 4] coordination-driven self-assembly of cyclometalated
iridium (III) using linear aryldiisocyanide bridging ligands (BLs). A family of nine new [Ir (C …

Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium (iii) complexes with imidazo [4, 5-f][1, 10] phenanthroline

K Choroba, J Palion-Gazda, M Penkala… - Dalton …, 2024 - pubs.rsc.org
This is a comprehensive study of the photophysical behaviour of heteroleptic iridium (III)
complexes with imidazo [4, 5-f][1, 10] phenanthroline (imphen) as an ancillary ligand …

Amplification of circularly polarized luminescence from chiral cyclometalated platinum (II) complexes by the formation of excimer

J Han, Y Wang, J Wang, C Wu, X Zhang… - Journal of Organometallic …, 2022 - Elsevier
Circularly polarized organic light-emitting diodes (CP-OLEDs) have raised increasing
interests owing to their potential application in next-generation displays. In this work, by …

Excited-State Dynamics of Iridium (III): Applications in Chemistry

ME Olumba - 2023 - uh-ir.tdl.org
Iridium has over the last half-century proven to be a critical material necessary to sustain
many of the technologies of our modern world. Iridium's uses in optoelectronic and photonic …