Entropy engineering and tunable magnetic order in the spinel high-entropy oxide

GHJ Johnstone, MU González-Rivas… - Journal of the …, 2022 - ACS Publications
Spinel oxides are an ideal setting to explore the interplay between configurational entropy,
site selectivity, and magnetism in high-entropy oxides (HEOs). In this work, we characterize …

Suppression of antiferromagnetic order by strain-enhanced frustration in honeycomb cobaltate

GH Kim, M Park, S Samanta, U Choi, B Kang, U Seo… - Science …, 2024 - science.org
Layered honeycomb cobaltates are predicted as promising for realizing the Kitaev quantum
spin liquid, a many-body quantum entangled ground state characterized by fractional …

Selective Catalytic Hydrogenation of Fatty Acids with Cobalt–Halloysite Nanocomposites for Waste Valorization

A Serrano-Maldonado, A Bendounan… - ACS Applied Nano …, 2023 - ACS Publications
Environmentally friendly catalytic composites based on cobalt and a natural clay as
catalytically active phase and support, respectively, are herein reported for the valorization …

Quantitative analysis of the oxidation state of cobalt oxides by resonant photoemission spectroscopy

Y Lykhach, S Piccinin, T Skála, M Bertram… - The Journal of …, 2019 - ACS Publications
Quantitative assessment of the charge transfer phenomena in cobalt oxides and cobalt
complexes is essential for the design of advanced catalytic materials. We propose a method …

Co Polyoxometalates and a Co3O4 Thin Film Investigated by L-Edge X-ray Absorption Spectroscopy

AM Hibberd, HQ Doan, EN Glass… - The Journal of …, 2015 - ACS Publications
We have performed cobalt L-edge X-ray absorption spectroscopy (XAS) on important
materials for photoactive catalysis, namely nanoscale cobalt polyoxometalates (Co POM) …

Detailed Characterization of a Nanosecond-Lived Excited State: X-ray and Theoretical Investigation of the Quintet State in Photoexcited [Fe(terpy)2]2+

G Vanko, A Bordage, M Papai, K Haldrup… - The Journal of …, 2015 - ACS Publications
Theoretical predictions show that depending on the populations of the Fe 3d xy, 3d xz, and
3d yz orbitals two possible quintet states can exist for the high-spin state of the …

A close look at dose: Toward L-edge XAS spectral uniformity, dose quantification and prediction of metal ion photoreduction

MM Van Schooneveld, S DeBeer - Journal of Electron Spectroscopy and …, 2015 - Elsevier
This paper represents a call to the broader XAS community to more closely assess dose, as
well as the other experimental factors (detection method, temperature, pressure and sample …

Mn and Co Charge and Spin Evolutions in LaMn1–xCoxO3 Nanoparticles

M Ghiasi, MU Delgado-Jaime… - The Journal of …, 2016 - ACS Publications
The charge and spin-state evolution of manganese and cobalt in the LaMn1–x Co x O3 (x=
0.00, 0.25, 0.50, 0.75, and 1.00) perovskite nanoparticles have been studied with soft X-ray …

Influence of crystal structure, ligand environment and morphology on Co L-edge XAS spectral characteristics in cobalt compounds

DK Bora, X Cheng, M Kapilashrami… - Journal of …, 2015 - journals.iucr.org
The electronic structure of a material plays an important role in its functionality for different
applications which can be probed using synchrotron-based spectroscopy techniques. Here …

Spin-orbit excitons in CoO

PM Sarte, M Songvilay, E Pachoud, RA Ewings… - Physical Review B, 2019 - APS
CoO has an odd number of electrons in its unit cell, and therefore is expected to be metallic.
Yet, CoO is strongly insulating owing to significant electronic correlations, thus classifying it …