Trinuclear Cage‐Like ZnII Macrocyclic Complexes: Enantiomeric Recognition and Gas Adsorption Properties
Three zinc (II) ions in combination with two units of enantiopure [3+ 3] triphenolic Schiff‐base
macrocycles 1, 2, 3, or 4 form cage‐like chiral complexes. The formation of these complexes …
macrocycles 1, 2, 3, or 4 form cage‐like chiral complexes. The formation of these complexes …
Discrete {Gd III 4 M}(M= Gd III or Co II) pentanuclear complexes: a new class of metal-organophosphate molecular coolers
The first examples of homo-and hetero-polymetallic organophosphates of gadolinium are
reported. Magnetic measurements reveal a higher magnetic entropy change for the isotropic …
reported. Magnetic measurements reveal a higher magnetic entropy change for the isotropic …
Ceramic and porous framework metal silicates and phosphates from molecular precursors: an ever-evolving ambient synthesis approach
R Murugavel - Emergent Materials, 2019 - Springer
Metal oxides, silicates and phosphates represent three of the major classes of materials
which have been extensively investigated owing to their enormous application potential …
which have been extensively investigated owing to their enormous application potential …
Permanent Porosity Derived From the Self‐Assembly of Highly Luminescent Molecular Zinc Carbonate Nanoclusters
K Sokołowski, W Bury, I Justyniak… - Angewandte …, 2013 - Wiley Online Library
Over the past two decades, crystalline microporous materials have attracted major interest,
owing to their applications in gas sorption, separation, catalysis, and sensing.[1] …
owing to their applications in gas sorption, separation, catalysis, and sensing.[1] …
Development of a 2D Network of Zinc Organophosphate with an 8-Membered Ring Core Having Corrosion Resistance Properties
A 2D framework, ie, zinc organophosphate [Zn (tmbiph)(solv)] 2 (tmbiphH4= tetramethyl-[1,
1′-biphenyl]-4, 4′-diyl bis (dihydrogen phosphate); solv= 2H2O) with an eight-membered …
1′-biphenyl]-4, 4′-diyl bis (dihydrogen phosphate); solv= 2H2O) with an eight-membered …
Fluoride ion sensing and caging by a preformed molecular D4R zinc phosphate heterocubane
AC Kalita, R Murugavel - Inorganic chemistry, 2014 - ACS Publications
Double-4-ring (D4R) zinc phosphate [Zn (dipp)(DMSO)] 4 (1, dipp= 2, 6-di-iso-
propylphenylphosphate, DMSO= dimethyl sulfoxide), on treatment with a free fluoride ion …
propylphenylphosphate, DMSO= dimethyl sulfoxide), on treatment with a free fluoride ion …
Octanuclear zinc phosphates with hitherto unknown cluster architectures: ancillary ligand and solvent assisted structural transformations thereof
Structural variations in zinc phosphate cluster chemistry have been achieved through a
careful selection of phosphate ligand, ancillary ligand, and solvent medium. The use of 4 …
careful selection of phosphate ligand, ancillary ligand, and solvent medium. The use of 4 …
Discrete and polymeric cobalt organophosphates: isolation of a 3-D cobalt phosphate framework exhibiting selective CO 2 capture
Structurally diverse mononuclear, dinuclear, and tetranuclear cobalt organophosphates and
a three-dimensional framework based on a D4R cobalt phosphate are reported. The role of …
a three-dimensional framework based on a D4R cobalt phosphate are reported. The role of …
[PDF][PDF] Cinchona alkaloid-metal complexes: noncovalent porous materials with unique gas separation properties
A particularly demanding task in the area of hybrid organic–inorganic materials has been
the engineering of well-defined void nanospaces [1] capable of selectively binding a guest …
the engineering of well-defined void nanospaces [1] capable of selectively binding a guest …
Ab initio chemical synthesis of designer metal phosphate frameworks at ambient conditions
Stepwise hierarchical and rational synthesis of porous zinc phosphate frameworks by
predictable and directed assembly of easily isolable tetrameric zinc phosphate [Zn …
predictable and directed assembly of easily isolable tetrameric zinc phosphate [Zn …