Comproportionation and disproportionation in nickel and copper complexes

CS Day, R Martin - Chemical Society Reviews, 2023 - pubs.rsc.org
Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Bimetallic cooperation across the periodic table

J Campos - Nature Reviews Chemistry, 2020 - nature.com
Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Cooperative effects in multimetallic complexes applied in catalysis

R Maity, BS Birenheide, F Breher, B Sarkar - ChemCatChem, 2021 - Wiley Online Library
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Recent advances in nickel catalysis enabled by stoichiometric metallic reducing agents

E Richmond, J Moran - Synthesis, 2018 - thieme-connect.com
This short review describes recent advances in the field of nickel catalysis, specifically
transformations employing stable Ni (II) precatalysts that are activated in situ with the use of …

Complexes of Ni (I): a “rare” oxidation state of growing importance

CY Lin, PP Power - Chemical Society Reviews, 2017 - pubs.rsc.org
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

M Navarro, JJ Moreno, M Pérez-Jiménez… - Chemical …, 2022 - pubs.rsc.org
There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

Deoxygenative haloboration and enantioselective chloroboration of carbonyls

D Wang, J Zhou, Z Hu, T Xu - Journal of the American Chemical …, 2022 - ACS Publications
Deoxygenative difunctionalization of carbonyls affords a straightforward and effective route
to construct geminal dual functionalized motifs. However, the research in this field is very …

Tuning metal–metal interactions for cooperative small molecule activation

Q Wang, SH Brooks, T Liu, NC Tomson - Chemical Communications, 2021 - pubs.rsc.org
Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Ti-catalyzed radical alkylation of secondary and tertiary alkyl chlorides using Michael acceptors

X Wu, W Hao, KY Ye, B Jiang, G Pombar… - Journal of the …, 2018 - ACS Publications
Alkyl chlorides are common functional groups in synthetic organic chemistry. However, the
engagement of unactivated alkyl chlorides, especially tertiary alkyl chlorides, in transition …