Recent progress in Pd-based nanocatalysts for selective hydrogenation

X Zhao, Y Chang, WJ Chen, Q Wu, X Pan, K Chen… - ACS …, 2021 - ACS Publications
Selective hydrogenation plays an important role in the chemical industry and has a wide
range of applications, including the production of fine chemicals and petrochemicals …

Manipulating the microenvironment of surfactant-encapsulated Pt nanoparticles to promote activity and selectivity

G Li, N Marinkovic, B Wang, MR Komarneni… - ACS …, 2022 - ACS Publications
Precise tuning of the local environment surrounding the active site is key to engineering
catalytic materials. Here, we have explored a nanoconfined catalytic system that exhibits …

Selective hydrogenation of the CC bond in cinnamaldehyde over an ultra-small Pd-Ag alloy catalyst

R Li, W Yao, Y Jin, W Jia, X Chen, J Chen… - Chemical Engineering …, 2018 - Elsevier
Hydrocinnamaldehyde (HCAL) is a crucial intermediate in the manufacture of perfumes and
pharmaceuticals, but highly selective hydrogenation of cinnamaldehyde (CALD) to …

Acrolein Hydrogenation Catalyzed by Pt (111): Effect of Carbonaceous Deposits on Kinetics

MT Nayakasinghe, Y Xu, F Zaera - ACS Catalysis, 2023 - ACS Publications
Absolute turnover frequencies for the hydrogenation of acrolein were measured by using a
Pt (111) single crystal as the catalyst. The kinetics of the reaction were found to be …

Solvent effects on heterogeneous catalysis in the selective hydrogenation of cinnamaldehyde over a conventional Pd/C catalyst

Y Li, H Cheng, W Lin, C Zhang, Q Wu… - Catalysis Science & …, 2018 - pubs.rsc.org
Solvent effects in the selective hydrogenation of an α, β-unsaturated aldehyde of
cinnamaldehyde (CAL) were investigated under gas–liquid–solid reaction conditions. A …

Efficient Pt–FeO x/TiO 2@ SBA-15 catalysts for selective hydrogenation of cinnamaldehyde to cinnamyl alcohol

Y Xue, R Yao, J Li, G Wang, P Wu, X Li - Catalysis Science & …, 2017 - pubs.rsc.org
TiO2 was coated onto mesoporous silica SBA-15 by hydrolysis of tetrabutyl titanate to
prepare 15 wt% TiO2@ SBA-15 composites (15TS). The 15TS composites retain the …

Spatial Location and Microenvironment Engineering of Pt-CeO2 Nanoreactors for Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol

L Wang, R Han, Y Ma, MS Duyar, W Liu… - The Journal of Physical …, 2021 - ACS Publications
More than 25% of chemical transformations involve at least one hydrogenation step.
Selective hydrogenation of unsaturated aldehydes is an essential process in the industrial …

Bifunctional metal–acid sites on nickel boride catalysts: Phenol hydrodeoxygenation and water-promoted C= C hydrogenation

G Li, T Salas, S Sun, B Wang, MR Komarneni… - Journal of …, 2024 - Elsevier
Modification of earth-abundant metal catalysts with optimized catalytic performance can be
potential alternatives to precious metal catalysts for more sustainable processes. Using a …

Pd and PdZn supported on ZnO as catalysts for the hydrogenation of cinnamaldehyde to hydrocinnamyl alcohol

S Fujita, H Mitani, C Zhang, K Li, F Zhao, M Arai - Molecular Catalysis, 2017 - Elsevier
Liquid phase selective hydrogenation of cinnamaldehyde (CAL) was investigated over ZnO-
supported Pd and PdZn catalysts different in the Pd loading. The former monometallic …

In-situ synthesis of Ni nanoparticles confined within SiO2 networks with interparticle mesopores with enhanced selectivity for cinnamaldehyde hydrogenation

F Wang, Y Bi, N Chen, K Hu, X Wei - Chemical Physics Letters, 2018 - Elsevier
Ni nanoparticles (NPs) confined within SiO 2 networks with interparticle mesopores (Ni/SiO
2-IS) were successfully synthesized via in-situ process with a combination of azeotropic …