The kinetics of metal oxide photoanodes from charge generation to catalysis
Generating charge carriers with lifetimes long enough to drive catalysis is a critical aspect for
photoelectrochemical and photocatalytic systems, and a key determinant of their efficiency …
photoelectrochemical and photocatalytic systems, and a key determinant of their efficiency …
Molecular catalysts for water oxidation
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …
Dynamic active-site generation of atomic iridium stabilized on nanoporous metal phosphides for water oxidation
K Jiang, M Luo, M Peng, Y Yu, YR Lu, TS Chan… - Nature …, 2020 - nature.com
Designing efficient single-atom catalysts (SACs) for oxygen evolution reaction (OER) is
critical for water-splitting. However, the self-reconstruction of isolated active sites during …
critical for water-splitting. However, the self-reconstruction of isolated active sites during …
Iridium-based double perovskites for efficient water oxidation in acid media
O Diaz-Morales, S Raaijman, R Kortlever… - Nature …, 2016 - nature.com
The development of active, cost-effective and stable oxygen-evolving catalysts is one of the
major challenges for solar-to-fuel conversion towards sustainable energy generation. Iridium …
major challenges for solar-to-fuel conversion towards sustainable energy generation. Iridium …
Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
The electrochemical conversion of carbon dioxide and water into useful products is a major
challenge in facilitating a closed carbon cycle. Here we report a cobalt protoporphyrin …
challenge in facilitating a closed carbon cycle. Here we report a cobalt protoporphyrin …
Identifying metal-oxo/peroxo intermediates in catalytic water oxidation by in situ electrochemical mass spectrometry
Molecular catalysis of water oxidation has been intensively investigated, but its mechanism
is still not yet fully understood. This study aims at capturing and identifying key short-lived …
is still not yet fully understood. This study aims at capturing and identifying key short-lived …
Water in N-heterocyclic carbene-assisted catalysis
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
Iridium-based complexes for water oxidation
JM Thomsen, DL Huang, RH Crabtree… - Dalton …, 2015 - pubs.rsc.org
Organometallic Ir precatalysts have been found to yield homogeneous Ir-based water-
oxidation catalysts (WOCs) with very high activity. The Cp* Ir catalyst series can operate …
oxidation catalysts (WOCs) with very high activity. The Cp* Ir catalyst series can operate …
Total water splitting catalyzed by Co@ Ir core–shell nanoparticles encapsulated in nitrogen-doped porous carbon derived from metal–organic frameworks
Developing bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen
evolution reaction (HER) toward overall water splitting with high efficiency and robust …
evolution reaction (HER) toward overall water splitting with high efficiency and robust …
Redox-State Kinetics in Water-Oxidation IrOx Electrocatalysts Measured by Operando Spectroelectrochemistry
Hydrous iridium oxides (IrO x) are the best oxygen evolution electrocatalysts available for
operation in acidic environments. In this study, we employ time-resolved operando …
operation in acidic environments. In this study, we employ time-resolved operando …