Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Environmental pollution is a significant cause of disease throughout the globe, but the
dangers are disproportionately greater in developing nations due to poverty, a lack of …

Direct conversion of C–H bonds into C–C bonds is a promising alternative to the
conventional cross-coupling reactions, thus giving rise to a wide range of efficient catalytic C …

Ruthenaelectro (II/IV)-catalyzed intermolecular C–H acyloxylations of phenols have been
developed by guidance of experimental, CV and computational insights. The use of …

Herein, we describe the development of a Rh-catalyzed C–H acyloxylation under mild
electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was …

Rhodium‐electrocatalyzed arene C− H oxygenation by weakly O‐coordinating amides and
ketones have been established by bimetallic electrocatalysis. Likewise, diverse …

We report herein a series of tailored CpXRh (LX) Cl catalyst systems for the outer-sphere C–
H amidations discovered by high-throughput experimentation. Using a diverse repertoire of …

Transition‐metal‐catalyzed C− H functionalization is one of the fascinating scientific fronts in
organic synthesis for the formation of conjugated arenes and has emerged as a benchmark …