The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

The interesting and diverse biological activities of nitrogen-containing compounds make the
construction of the C–N bond of great importance. Despite the tremendous advances that …

A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles
and ketones has been developed. These reactions rely on the oxidative generation of iminyl …

A room‐temperature, visible‐light‐driven N‐centered iminyl radical‐mediated and redox‐
neutral C− C single bond cleavage/radical addition cascade reaction of oxime esters and …

The formation and use of iminyl radicals in novel and divergent hydroimination and
iminohydroxylation cyclization reactions has been accomplished through the design of a …

At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

The first example of intermolecular olefination of cyclobutanone oximes with alkenes via
selective C− C bond cleavage leading to the synthesis of nitriles in the presence of a cheap …

Although the transition metal-catalyzed radical fluorine atom transfer (FAT) strategy has
emerged as a powerful tool for the construction of C–F bonds, to our knowledge, this …

An iron‐catalyzed coupling reaction of O‐acyloximes and O‐benzoyl amidoximes with silyl
enol ethers is reported. The protocol provides access to functionalized pyrroles, 1, 6 …

Conventional approaches to Pd-catalyzed alkene 1, 2-carboamination rely upon the
combination of a nucleophilic nitrogen-based component and an internal C-based or …