Penetrant-induced plasticization in microporous polymer membranes

KM Rodriguez, S Lin, AX Wu, KR Storme… - Chemical Society …, 2024 - pubs.rsc.org
Penetrant-induced plasticization has prevented the industrial deployment of many polymers
for membrane-based gas separations. With the advent of microporous polymers, new …

State-of-the-art poly aryl sulfone (PAS)-based membranes for gas separation: A review on molecular design and structural engineering

MAA Shahmirzadi, A Kargari, T Matsuura - Journal of Industrial and …, 2024 - Elsevier
Poly aryl sulfone (PAS) polymers are important as a commercial engineering class of
polymers due to their superb physicochemical properties, extensively used for fabricating …

Tuning Porosity in Triptycene-Poly (arylene ether) s

KR Storme, BS Schreib, ZP Smith, TM Swager - Macromolecules, 2024 - ACS Publications
We report a scalable synthesis of high-molecular-weight poly (arylene ether) s (PAEs) using
decafluorobiphenyl under SNAr reaction conditions and the preparation of enantiopure (R …

Unprecedented gas separation performance of a difluoro-functionalized triptycene-based ladder PIM membrane at low temperature

X Ma, Z Zhu, W Shi, W Ji, J Li, Y Wang… - Journal of Materials …, 2021 - pubs.rsc.org
Advanced membrane materials are playing increasingly important roles in solving global
energy intensive separation problems. Herein, we introduce a high-performance intrinsically …

The mechanism of light gas transport through configurational free volume in glassy polymers

WJ Box, Z Huang, R Guo, M Galizia - Journal of Membrane Science, 2022 - Elsevier
A possible mechanism of small molecule transport in glassy polymer membranes containing
configurational free volume (ie, triptycene moieties) is proposed. To this aim, a family of …

A microporous poly (arylene ether) platform for membrane‐based gas separation

S Guo, JY Yeo, FM Benedetti, D Syar… - Angewandte …, 2024 - Wiley Online Library
Membrane‐based gas separations are crucial for an energy‐efficient future. However, it is
difficult to develop membrane materials that are high‐performing, scalable, and …

From a hyperbranched polyimide to a microporous network polyimide via reaction temperature change and its application in gas separation membranes

S Liu, J Luo, G Deng, Y Wang, X Liu… - Polymers for …, 2021 - Wiley Online Library
We prepared a series of microporous network polyimides (MN‐PIs) derived from tris (4‐
aminophenyl) amine (TAPA), and three commercial dianhydrides such as 4, 4 …

Data: Diafiltration apparatus for high-throughput analysis

JA Ouimet, X Liu, DJ Brown, EA Eugene… - Journal of membrane …, 2022 - Elsevier
Improved characterization techniques, which address knowledge gaps related to the
interfacial processes that govern solute–solute selectivity and the performance of …

Room temperature synthesis, characterization and enhanced gas transport properties of novel poly (oxindolylidene arylene) s with dibenzothiophene …

E Cetina-Mancilla, C Camacho-Zuñiga… - Separation and …, 2024 - Elsevier
Aromatic sulfur-containing polymers poly (arylene ether sulfone) s and poly (arylene sulfide
sulfone) s are widely used in membrane-based gas-and liquid separations and purification …

Device for the Acquisition of Dynamic Data Enables the Rapid Characterization of Polymer Membranes

ZW Muetzel, JA Ouimet, WA Phillip - ACS Applied Polymer …, 2022 - ACS Publications
Creating systems and techniques capable of reducing the time, energy, and resources
needed to characterize the transport properties of polymer membranes can help to increase …