Synthetic applications of proton-coupled electron transfer
EC Gentry, RR Knowles - Accounts of chemical research, 2016 - ACS Publications
Conspectus Redox events in which an electron and proton are exchanged in a concerted
elementary step are commonly referred to as proton-coupled electron transfers (PCETs) …
elementary step are commonly referred to as proton-coupled electron transfers (PCETs) …
Ultrafast electron dynamics in solar energy conversion
Electrons are the workhorses of solar energy conversion. Conversion of the energy of light to
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …
Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen
The synthesis of weak chemical bonds at or near thermodynamic potential is a fundamental
challenge in chemistry, with applications ranging from catalysis to biology to energy science …
challenge in chemistry, with applications ranging from catalysis to biology to energy science …
Excited-state proton-coupled electron transfer: different avenues for promoting proton/electron movement with solar photons
Excited-state proton-coupled electron transfer (ES-PCET) is a promising avenue for solar
fuel production and small molecule activation. Although less is known about ES-PCET …
fuel production and small molecule activation. Although less is known about ES-PCET …
Photobasic transition-metal complexes
O Bysewski, M Sittig, A Winter, B Dietzek-Ivanšić… - Coordination Chemistry …, 2024 - Elsevier
Transition-metal complexes, which exhibit photobasic properties, are highly promising for
chemical applications where the proton abstraction represents one key step. Photobases …
chemical applications where the proton abstraction represents one key step. Photobases …
Taming tris (bipyridine) ruthenium (II) and its reactions in water by capture/release with shape-switchable symmetry-matched cyclophanes
Electron/proton transfers in water proceeding from ground/excited states are the elementary
reactions of chemistry. These reactions of an iconic class of molecules─ polypyridineRu …
reactions of chemistry. These reactions of an iconic class of molecules─ polypyridineRu …
Photoinduced electron transfer coupled to donor deprotonation and acceptor protonation in a molecular triad mimicking photosystem II
A Pannwitz, OS Wenger - Journal of the American Chemical …, 2017 - ACS Publications
The first artificial donor–sensitizer–acceptor compound in which photoinduced long-range
electron transfer is coupled to donor deprotonation and acceptor protonation is reported …
electron transfer is coupled to donor deprotonation and acceptor protonation is reported …
CO2 Activation with Manganese Tricarbonyl Complexes through an H‐Atom Responsive Benzimidazole Ligand
Herein, we report the synthesis and characterization of two manganese tricarbonyl
complexes, MnI (HL)(CO) 3Br (1 a‐Br) and MnI (MeL)(CO) 3Br (1 b‐Br)(where HL= 2‐(2' …
complexes, MnI (HL)(CO) 3Br (1 a‐Br) and MnI (MeL)(CO) 3Br (1 b‐Br)(where HL= 2‐(2' …
Intermolecular Proton-Coupled Electron Transfer Reactivity from a Persistent Charge-Transfer State for Reductive Photoelectrocatalysis
P Garrido-Barros, CG Romero… - Journal of the …, 2024 - ACS Publications
Interest in applying proton-coupled electron transfer (PCET) reagents in reductive electro-
and photocatalysis requires strategies that mitigate the competing hydrogen evolution …
and photocatalysis requires strategies that mitigate the competing hydrogen evolution …
Optical sensing of anions via supramolecular recognition with biimidazole complexes
SA Rommel, D Sorsche… - … –A European Journal, 2017 - Wiley Online Library
Phosphorescent metal complexes with peripheral N‐H donor functionalities have attracted
great attention as potential molecular sensing units for anionic species lately. In this …
great attention as potential molecular sensing units for anionic species lately. In this …