Fine tuning of electrosynthesis pathways by modulation of the electrolyte solvation structure

F Dorchies, A Grimaud - Chemical Science, 2023 - pubs.rsc.org
Electrosynthesis is a method of choice for designing new synthetic routes owing to its ability
to selectively conduct reactions at controlled potentials, high functional group tolerance, mild …

Direct imaging of micrometer-thick interfaces in salt–salt aqueous biphasic systems

D Degoulange, R Pandya… - Proceedings of the …, 2023 - National Acad Sciences
Unlike the interface between two immiscible electrolyte solutions (ITIES) formed between
water and polar solvents, molecular understanding of the liquid–liquid interface formed for …

Stability and structure of the aqueous LiTFSI–LiCl interface

HO Wood, HM Burnett, RAW Dryfe, P Carbone - Faraday Discussions, 2024 - pubs.rsc.org
It has recently been demonstrated that aqueous lithium bis (trifluoromethanesulfonyl) imide
(LiTFSI) and lithium chloride (LiCl) solutions can form stable liquid–liquid biphasic systems …

Extending insertion electrochemistry to soluble layered halides with superconcentrated electrolytes

N Dubouis, T Marchandier, G Rousse, F Marchini… - Nature Materials, 2021 - nature.com
Insertion compounds provide the fundamental basis of today's commercialized Li-ion
batteries. Throughout history, intense research has focused on the design of stellar …

Two-Step Mechanism for Halogen Intercalation in Graphite Enabled by Aqueous Biphasic Systems

D Degoulange, G Rousse, A Grimaud - ACS Energy Letters, 2023 - ACS Publications
The electrification of our society requires safer and longer-lasting batteries, for which
modular electrolytes, such as aqueous biphasic systems (ABS), are being developed. ABS …

Water-in-salt: fast dynamics, structure, thermodynamics, and bulk properties

L Kacenauskaite, SJ Van Wyck… - The Journal of …, 2023 - ACS Publications
We present concentration-dependent dynamics of highly concentrated LiBr solutions and
LiCl temperature-dependent dynamics for two high concentrations and compare the results …

Revisiting the driving force inducing phase separation in PEG–phosphate aqueous biphasic systems

S Bonnassieux, R Pandya, DA Skiba… - Faraday …, 2024 - pubs.rsc.org
Liquid phase separation using aqueous biphasic systems (ABS) is widely used in industrial
processes for the extraction, separation and purification of macromolecules. Using water as …

Fate of metal ions in PEG-400/Na2SO4/H2O aqueous biphasic system: From eviction to extraction towards the upper polymer-rich phase

E Sinoimeri, AC Pescheux, I Guillotte, J Cognard… - Separation and …, 2023 - Elsevier
The fate of eight metal ions, Co (II), Cr (III), Cr (VI), Cu (II), Fe (III), Mn (II), Mo (VI) and Ni (II),
introduced as minor components in the well-known aqueous biphasic system PEG-400/Na 2 …

[HTML][HTML] Membraneless biphasic redox flow batteries: Interfacial effects and generalisation of the chemistry

A Ejigu, A Elgendy, HA Al Nasser, K Jupp, RAW Dryfe - Electrochimica Acta, 2025 - Elsevier
The wider adoption of redox flow batteries (RFBs) is hindered partly by the high cost of ion-
exchange membranes. Membrane-free batteries have recently emerged as a potential …

Separation of rare earths and transition metals using ionic-liquid-based aqueous biphasic systems

X Li, JJMM van de Ven, Z Li… - Industrial & Engineering …, 2022 - ACS Publications
An aqueous biphasic system (ABS) based on the ionic liquid (IL)
tributyltetradecylphosphonium chloride ([P444, 14] Cl) has been developed for the …