Iodine-catalyzed transformation of molecules containing oxygen functional groups

M Jereb, D Vražič, M Zupan - Tetrahedron, 2011 - Elsevier
Iodine has been attracting much attention since its discovery in 1811. It is the weakest
oxidizer among the halogens and a poor electrophile that often needs the assistance of a …

Rational design of catalysts for heterogeneous selective hydrogenation of unsaturated aldehydes/ketones: From nanoparticles to single atoms

M Deng, D Wang, Y Li - Applied Catalysis A: General, 2023 - Elsevier
Selective hydrogenation of unsaturated aldehydes/ketones (UAL) to unsaturated alcohols
(UOL) is a crucial reaction process in the fine chemical industry. Numerous efforts have …

Bioactive constituents from Chinese natural medicines. XXVIII. Chemical structures of acyclic alcohol glycosides from the roots of Rhodiola crenulata

S Nakamura, X Li, H Matsuda… - Chemical and …, 2008 - jstage.jst.go.jp
Chart 1. Structures of Constituents from the Roots of R. crenulata roots) was partitioned into
an EtOAc–H2O mixture to furnish an EtOAc-soluble fraction (11.6%) and aqueous layer. The …

Pentamethylcyclopentadienyl ruthenium: an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds

A Bouziane, B Carboni, C Bruneau, F Carreaux… - Tetrahedron, 2008 - Elsevier
The catalytic activity of the ruthenium (II) complex [RuCp∗(CH3CN) 3][PF6] 1 in the
transposition of allylic alcohols into carbonyl compounds, in acetonitrile, is reported. This …

Continuous Flow Process for Carbonyl and α,β-Unsaturated Carbonyl Compounds Reduction Using NaBH4 Solutions: Toward Implementation of Luche Reduction in …

V Bernardin, R Philippe, L Vanoye… - Industrial & …, 2024 - ACS Publications
Carbonyl reductions using NaBH4 are generally high-yielding and highly selective
processes commonly used in organic synthesis and the pharmaceutical industry. However …

Remote Stereocontrol Mediated by a Sulfinyl Group: Synthesis of Allylic Alcohols via Chemoselective and Diastereoselective Reduction of γ-Methylene δ …

JLG Ruano, MÁ Fernández-Ibáñez… - The Journal of …, 2009 - ACS Publications
The efficiency of the sulfinyl group as a remote controller of the chemoselectivity and
diastereoselectivity of the reduction of α, β-unsaturated α-[2-(p-tolylsulfinyl) phenyl] …

[PDF][PDF] 分子碘催化的有机化学反应

张占辉, 刘庆彬 - 化学进展, 2006 - manu56.magtech.com.cn
分子碘催化的有机化学反应3 Page 1 收稿: 2005 年2 月, 收修改稿: 2005 年7 月 3 国家自然科学
基金(No. 20477009) 和河北省自然科学基金资助项目(B2005000151) 3 3 通讯联系人e2mail …

Efficient and scalable process for the synthesis of antihypercholesterolemic drug ezetimibe

Y Zhu, J Pan, S Zhang, Z Liu, D Ye… - Synthetic …, 2016 - Taylor & Francis
An efficient and scalable process for the synthesis of antihypercholesterolemic drug
ezetimibe through chiral Evans auxiliary (S)-4-phenyl-2-oxazolidinone is described. The key …

An oxepinone route to carbohydrate based oxepines

S Castro, CS Johnson, B Surana, MW Peczuh - Tetrahedron, 2009 - Elsevier
Oxepines are ring expanded analogs of glycals that can be used to prepare septanose
carbohydrates. A route to carbohydrate based oxepines that utilizes oxepinones as a key …

Sodium Borohydride–Solid LiClO4: An Effective Reagent for Reducing Aldehydes and Ketones in Aprotic Solvent

AZ Halimjani, MR Saidi - Synthetic communications, 2005 - Taylor & Francis
An efficient and simple method for the reduction of aldehydes, ketones and acid chlorides
has been accomplished by using NaBH4–solid LiClO4 in mild conditions at ambient …