Allenyl sulfones are versatile building blocks that readily partake in a variety of
transformations such as Michael additions, rearrangements, cycloadditions, electrophilic …

In the current extensive review, we pay special attention to the progress in the synthesis of 2
H‐azirine. Content is organized by several main approaches for the synthesis of 2 H …

A regio-and chemoselective sulfonylation of propargyl alcohols with sulfinamides in 1, 1, 1,
3, 3, 3-hexafluoroisopropanol (HFIP) was developed. It provided straightforward and mild …

Benzodithioloimines are reacted with arynes or alkynes substituted with electron-
withdrawing groups to afford the corresponding thianthrene or benzo [b][1, 4] dithiine …

An efficient and practical approach for the synthesis of triaryl allenyl sulfones from easily
accessible propargylic alcohols was developed, by using sodium sulfinates as a sulfonyl …

The synthesis and reactivity of tetrazol-5-yl-phosphorus ylides towards N-halosuccinimide/
TMSN3 reagent systems was explored, opening the way to new haloazidoalkenes bearing a …

The decomposition mechanism of vinyl azide (CH2CHN3) has been studied by calculations
of the electronic structure. In addition, a study based on the topology of the electron charge …

A base-mediated Neber reaction of enaminopyrazolones, which are the tautomers of 4-
acyloxime-2-pyrazolin-5-ones, with sulfonyl chlorides was achieved. With this developed …

(Z)-3-Azido-3-methoxycarbonyl-2-chloro-acrylophenone (MACBP) has been synthesized,
isolated in low temperature argon and xenon matrices and studied by FTIR spectroscopy …

We report an atom-economical domino synthesis of functionalized and stereodefined
dienes. This method hinges on an allylic alkylation–electrocyclic ring-opening sequence …