Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …
active and selective catalysts. Recently, C–H-active transformations using porous materials …
Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …
(MOFs) together with the facile tunability of their properties makes these materials suitable …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Biomimetic active sites on monolayered metal–organic frameworks for artificial photosynthesis
Enzymes have evolved to catalyse challenging chemical transformations with high efficiency
and selectivity. Although a number of artificial systems have been developed to recapitulate …
and selectivity. Although a number of artificial systems have been developed to recapitulate …
Trimetallic metal–organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion
Nowadays, there is much research focused on advanced technologies for energy storage
and conversion in order to mitigate environmental pollution and address concerns on future …
and conversion in order to mitigate environmental pollution and address concerns on future …
Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …
their physical and chemical properties, but it can be difficult to know which MOFs would be …
Catalysis by metal organic frameworks: perspective and suggestions for future research
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …
high densities of catalytic sites in high-area porous solids, some with stabilities at high …
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites
The separation of ethane from its corresponding ethylene is an important, challenging, and
energy-intensive process in the chemical industry. Here we report a microporous metal …
energy-intensive process in the chemical industry. Here we report a microporous metal …
Bimetallic metal–organic frameworks and their derivatives
Bimetallic metal–organic frameworks (MOFs) have two different metal ions in the inorganic
nodes. According to the metal distribution, the architecture of bimetallic MOFs can be …
nodes. According to the metal distribution, the architecture of bimetallic MOFs can be …