Synthetic strategies towards chiral coordination polymers

HM Tay, N Kyratzis, S Thoonen, SA Boer… - Coordination Chemistry …, 2021 - Elsevier
Chiral coordination polymers and porous chiral MOFs have great potential as agents for
enantioselective separations, sensing, and catalysis due to their well-structured internal …

Crystal structure of zinc coordination polymers based on 1, 4-diazabicyclo [2.2. 2] octane N, N′-dioxide: Effect of hydrophobicity of carboxylate ligands

PA Demakov, YA Yudina, DG Samsonenko… - Journal of Structural …, 2021 - Springer
Four novel coordination polymers based on 1, 4-diazabicyclo [2.2. 2] octane N, N′-dioxide
(odabco) with the following formulas [Zn (H 2 O) 2 (HCOO) 2]· odabco (1),[Zn 2 …

Chiral MOF incorporating chiral guests: Structural studies and enantiomer-dependent luminescent properties

MS Zavakhina, DG Samsonenko, DN Dybtsev… - Polyhedron, 2019 - Elsevier
Two new inclusion compounds of chiral guest molecules in chiral metal–organic framework
(MOF) were obtained by soaking the crystalline [Zn 2 (dmf)(bdc)(S-lac)]· DMF (dmf= N, N …

Urotropine as a ligand for the efficient synthesis of metal-organic frameworks

SA Sapchenko, MO Barsukova, TV Nokhrina… - Russian Chemical …, 2020 - Springer
Urotropine is a cheap and promising ligand for the synthesis of metal-organic frameworks
containing uncoordinated nitrogen atoms. The reactions between urotropine, dicarboxylic …

Role of the Auxiliary Ligand in the Spontaneous Resolution of Enantiomers in Three-Dimensional Coordination Polymers

HJ Chen, L Xu, MT Chen, LR Lin, GL Zhuang… - Inorganic …, 2021 - ACS Publications
Four pairs of chiral 3D coordination polymers (CPs),[Zn2 (BDC)(lac)(DMF)]· guest
(2)(H2BDC= benzene dicarboxylic acid; H2lac= lactic acid; guest= 1.5 DMF+ i-PrOH),[Co2 …

Crystal Structure of Metal-Organic Coordination Polymers Based on Potassium and Barium Cations with α-Cyclodextrin

EI Koshevoi, DG Samsonenko… - Journal of Structural …, 2020 - Springer
In the interaction of aqueous solutions of potassium and barium hydroxides or barium
chloride with α-cyclodextrin four layered coordination polymers are obtained and structurally …

Synthesis of water-soluble zinc(ii) nitrilotris(methylenephosphonate). Molecular structure of bis(4-carboxyphenylaminium) nitrilotris(methylenephosphonate) dihydrate

VV Semenov, NV Zolotareva, BI Petrov… - Russian Chemical …, 2020 - Springer
Nitrilotris (methylenephosphonic) acid N [CH 2 P (O)(OH) 2] 3 (H 6 L) reacts with zinc oxide
in an aqueous medium to give a poorly soluble polymeric crystalline salt (ZnH 4 L) n. The …

Inclusion Compound of Phthalic Anhydride in Porous Homochiral Zinc Terephthalate Lactate: The Effect of Guests on the Geometrical Characteristics of the Metal …

MS Zavakhina, IS Khan, DG Samsonenko… - Journal of Structural …, 2019 - Springer
The inclusion compound [Zn 2 (dmf)(bdc)(S-lac)]· 0.5 FTA (FTA= phthalic anhydride) is
obtained by keeping the crystals of porous homochiral metal-organic coordination polymer …

Crystal Structure Of Lithium, Potassium, And Calcium Complexes With Β-Cyclodextrine

EI Koshevoi, DG Samsonenko… - Journal of Structural …, 2021 - Springer
Three new coordination compounds are obtained in the reaction of aqueous solutions of
lithium and potassium hydroxides or calcium chloride with β-cyclodextrine. Their …

Tuning Enantioselective Drug Adsorption in Isoreticular Homochiral Metal-Peptide Frameworks through Proximity Pore Interactions

J Ho, A Yadav, A Gładysiak, A Carpenter, A Verma… - 2023 - chemrxiv.org
Pharmaceutical research places great importance on the stereochemistry and
enantioseparation of racemic drugs due to the potential variations in pharmacological and …