Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Recent developments of photoactive Cu (I) and Ag (I) complexes with diphosphine and related ligands

H Takeda, A Kobayashi, K Tsuge - Coordination Chemistry Reviews, 2022 - Elsevier
In the past two decades, emissive Cu (I) complexes have been synthesized with various
ligands, revealing their interesting and useful photophysical properties such as high …

Lessons learnt in photocatalysis–the influence of solvent polarity and the photostability of the photocatalyst

MA Bryden, F Millward, OS Lee, L Cork, MC Gather… - Chemical …, 2024 - pubs.rsc.org
Herein, we show that there is significant variation in both the triplet energies and redox
properties of photocatalysts as a function of solvent based on a study of eight PCs in four …

Thermally activated delayed fluorescence in luminescent cationic copper (i) complexes

C Sandoval-Pauker, M Santander-Nelli, P Dreyse - RSC advances, 2022 - pubs.rsc.org
In this work, the photophysical characteristics of [Cu (N^ N) 2]+ and [Cu (N^ N)(P^ P)]+
complexes were described. The concept of thermally activated delayed fluorescence (TADF) …

Thermally Activated Delayed Fluorescence (TADF) Materials Based on Earth‐Abundant Transition Metal Complexes: Synthesis, Design and Applications

V Ferraro, C Bizzarri, S Bräse - Advanced Science, 2024 - Wiley Online Library
Materials exhibiting thermally activated delayed fluorescence (TADF) based on transition
metal complexes are currently gathering significant attention due to their technological …

Dendri‐LEC Family: Establishing the Bright Future for Dendrimer Emitters in Traditional and Graphene‐Based Light‐Emitting Electrochemical Cells

LM Cavinato, K Yamaoka, S Lipinski… - Advanced Functional …, 2023 - Wiley Online Library
A rational implementation and optimization of thermally activated delayed fluorescent
(TADF) dendrimer emitters in light‐emitting electrochemical cells (LECs) sets in the Dendri …

Multivariate Analysis Identifying [Cu(N^N)(P^P)]+ Design and Device Architecture Enables First‐Class Blue and White Light‐Emitting Electrochemical Cells

LM Cavinato, S Wölfl, A Pöthig, E Fresta… - Advanced …, 2022 - Wiley Online Library
White light‐emitting electrochemical cells (LECs) comprising only [Cu (N^ N)(P^ P)]+ have
not been reported yet, as all the attempts toward blue‐emitting complexes failed. Multivariate …

A three-coordinate cuprous complex exhibiting both photochromic and fluorescent sensing properties, and some TD-DFT calculations

YF Jia, L Song, WZ Xu, JT Wu, HX Jin, YF Zhu… - Journal of Molecular …, 2023 - Elsevier
Photo-functional materials with photochromic and fluorescent properties are very attractive
because they have a wide range of applications. The design and research of fluorescent …

Closo- or Nido-Carborane Diphosphane as Responsible for Strong Thermochromism or Time Activated Delayed Fluorescence (TADF) in [Cu(N^N)(P^P)]0/+

A Alconchel, O Crespo, P García-Orduña… - Inorganic …, 2021 - ACS Publications
Ortho-closo or ortho-nido-carborane-diphosphanes have been selected to prepare the
heteroleptic cationic or neutral [Cu (N^ N){(PPh2) 2C2B10H10}] PF6 (1) and [Cu (N …

Three heteroleptic copper(I) complexes with [Cu(P˄P)N2]+ structure and their fluorescence sensing for VOCs

SY Tang, L Song, YF Jia, WZ Xu… - Applied …, 2023 - Wiley Online Library
The design and research of luminescent and volatile organic compound (VOC) fluorescent
sensing materials are of great significance and challenge. We report herein the ligand …