Recent advances in laser absorption and shock tube methods for studies of combustion chemistry

RK Hanson, DF Davidson - Progress in Energy and Combustion Science, 2014 - Elsevier
Recent advances in laser absorption and shock tube methodologies for studies of
combustion chemistry are reviewed. First the principles of shock tube operation are …

Roaming Reactions and Dynamics in the van der Waals Region

AG Suits - Annual Review of Physical Chemistry, 2020 - annualreviews.org
Roaming reactions were first clearly identified in photodissociation of formaldehyde 15 years
ago, and roaming dynamics are now recognized as a universal aspect of chemical reactivity …

Predictive a priori pressure-dependent kinetics

AW Jasper, KM Pelzer, JA Miller, E Kamarchik… - Science, 2014 - science.org
The ability to predict the pressure dependence of chemical reaction rates would be a great
boon to kinetic modeling of processes such as combustion and atmospheric chemistry. This …

Ignition and kinetic modeling of methane and ethane fuel blends with oxygen: A design of experiments approach

CJ Aul, WK Metcalfe, SM Burke, HJ Curran… - Combustion and …, 2013 - Elsevier
A series of shock-tube experiments and chemical kinetics modeling calculations were
performed to investigate the ignition behavior of methane and ethane with oxygen in regions …

Roaming

JM Bowman - Molecular Physics, 2014 - Taylor & Francis
In this review the roaming pathway in chemical reaction dynamics is described and
illustrated. After a brief review and illustration of this pathway, an update on the chemical …

A wide range experimental study and further development of a kinetic model describing propane oxidation

L Zhu, S Panigrahy, SN Elliott, SJ Klippenstein… - Combustion and …, 2023 - Elsevier
This work presents an experimental and kinetic modeling study of propane oxidation.
Ignition delay times of propane were measured in a high-pressure shock tube and in rapid …

It'sa gas: Oxidative dehydrogenation of propane over boron nitride catalysts

P Kraus, RP Lindstedt - The Journal of Physical Chemistry C, 2021 - ACS Publications
Boron nitride and related boron-containing materials have recently been suggested as very
promising catalysts in the oxidative dehydrogenation of propane. The high selectivity toward …

High-pressure oxidation of propane

H Hashemi, JM Christensen, LB Harding… - Proceedings of the …, 2019 - Elsevier
The oxidation properties of propane have been investigated by conducting experiments in a
laminar flow reactor at a pressure of 100 bar and temperatures of 500–900 K. The onset …

Thermal dissociation and roaming isomerization of nitromethane: experiment and theory

CJ Annesley, JB Randazzo… - The Journal of …, 2015 - ACS Publications
The thermal decomposition of nitromethane provides a classic example of the competition
between roaming mediated isomerization and simple bond fission. A recent theoretical …

Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a …

H Zhang, D Kaczmarek, C Rudolph, S Schmitt… - Combustion and …, 2022 - Elsevier
The potential of dimethyl ether (DME) and dimethoxymethane (DMM), representatives of the
attractive oxymethylene ether (OME) alternative fuel family, are explored here as reactivity …