Since the prediction of the existence of metallabenzenes in 1979, metallaaromatic chemistry
has developed rapidly, due to its importance in both experimental and theoretical fields …

Transition metal-containing metallabenzenes and metallabenzynes are organometallic
compounds derived from formal replacement of a CH group or a C atom in benzene and …

Aromatic compounds, such as benzene and its derivatives, porphyrins, fullerenes, carbon
nanotubes, and graphene, have numerous applications in biomedicine, materials science …

Indolizine-fused metallafuran and metal–quinolizinium complexes were synthesized from
reactions between dipicolinyl-substituted propargylic alcohol HC≡ CC (OH)(CH2 (2-py)) 2 …

Osmafuran complexes in the form of cis-[Os (L∧ L) 2 (C∧ O)]+(L∧ L= 1, 1-bis
(diphenylphosphino) methane (dppm) or 2, 2′-bipyridine (bpy); C∧ O=[C (CH3) C (CH3) …

Metallafuran complexes with a fused five‐membered phosphonium ring were synthesized
from reactions between terminal ynones HC≡ C (C= O) R and cis‐[Ru/Os (dppm) …

Abstract Alkali‐resistant osmabenzene [(SCN) 2 (PPh3) 2Os {CHC (PPh3) CHCICH}](2) can
undergo nucleophilic aromatic substitution with MeOH or EtOH to give cine‐substitution …

Based on isolobal analogy, the definition of metallafuran was described and its synthetic
chemistry was briefly summarized. In the structure of furan, when one of CH groups was …

The cis insertion of dimethyl acetylenedicarboxylate (DMAD, 2) into the Au–P bond of Au
(SAr)(PAr′ 3)(1) occurs selectively at room temperature to give adduct 3, whose X-ray …

We studied the reactivity of an osmium vinyl complex containing a coordinated hydroxyl
group OsCl 2 (PPh 3) 2 [CH= C (PPh 3)-CHPh (OH)](1) toward bidentate ligand 1, 4-bis …