Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Synthetic utility of biomimicking vanadium bromoperoxidase and n-tetrabutylammonium tribromide (TBATB) in organic synthesis

M Belal, S Sarkar, R Subramanian… - Organic & Biomolecular …, 2022 - pubs.rsc.org
Nature has established a broad spectrum of methods to introduce halogen atoms in organic
compounds. Recent developments have revealed that haloperoxidases are one of the major …

Fenton-like chemistry enables catalytic oxidative desulfurization of thioacetals and thioketals with hydrogen peroxide

G Zhao, Y Wang, C Wang, H Lei, B Yi, R Tong - Green Chemistry, 2022 - pubs.rsc.org
(di-) Thioacetals and (di-) thioketals serve commonly as protecting groups of carbonyls and
alcohols in organic synthesis, and therefore require highly efficient and chemoselective …

Total synthesis of (−)-enigmazole A

Y Ai, MV Kozytska, Y Zou, AS Khartulyari… - Journal of the …, 2015 - ACS Publications
A highly convergent, stereocontrolled total synthesis of the architecturally complex marine
sponge metabolite (−)-enigmazole A has been achieved. Highlights include an …

Visible-light mediated facile dithiane deprotection under metal free conditions

PD Dharpure, A Bhowmick, PK Warghude, RG Bhat - Tetrahedron Letters, 2020 - Elsevier
Visible light mediated facile and selective dithiane deprotection under metal free conditions
is developed. Eosin Y (1 mol%) proved to be an effective catalyst for the dithiane …

Total synthesis of the marine phosphomacrolide,(−)-Enigmazole A, exploiting multicomponent Type I Anion Relay Chemistry (ARC) in conjunction with a late-stage …

Y Ai, MV Kozytska, Y Zou, AS Khartulyari… - The Journal of …, 2018 - ACS Publications
An effective late-stage large-fragment union/rearrangement exploiting the Petasis–Ferrier
protocol, in conjunction with multicomponent Type I Anion Relay Chemistry (ARC) to access …

Tris (acetylacetonato) Iron (III): Recent Developments and Synthetic Applications

D Lübken, M Saxarra, M Kalesse - Synthesis, 2019 - thieme-connect.com
Tris (acetylacetonato) iron (III)[Fe (acac) 3] is an indispensable reagent in synthetic
chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions …

Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization

K Nishino, K Minato, T Miyazaki… - The Journal of Organic …, 2017 - ACS Publications
In this study an InI3-TMDS (1, 1, 3, 3-tetramethyldisiloxane) reducing system effectively
catalyzed the reductive dithioacetalization of a variety of aromatic and aliphatic carboxylic …

Recent Progress on the Mild Deprotection of Dithioketals, Dithioacetals, and Oxathiolanes

J Yan, JL Pozzo, A Hamze… - European Journal of …, 2022 - Wiley Online Library
Reactions for the deprotection of carbonyl derivatives have been of considerable interest to
the scientific community. In recent years efforts have been made to develop mild …

Chloral hydrate as a water carrier for the efficient deprotection of acetals, dithioacetals, and tetrahydropyranyl ethers in organic solvents

S Chandrasekhar, A Shrinidhi - Synthetic Communications, 2014 - Taylor & Francis
The efficient deprotection of several acetals, dithioacetals, and tetrahydropyranyl (THP)
ethers under ambient conditions, using chloral hydrate in hexane, is described. Excellent …