N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry

A Doddi, M Peters, M Tamm - Chemical reviews, 2019 - ACS Publications
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Pincer ligands—Tunable, versatile and applicable

MAW Lawrence, KA Green, PN Nelson, SC Lorraine - Polyhedron, 2018 - Elsevier
Pincer ligands continue to generate interest owing to the unusual properties they impart on
metal centers and consequently on the complexes they are involved in. These ligands and …

The role of zinc (II) ion in fluorescence tuning of tridentate pincers: A review

R Diana, B Panunzi - Molecules, 2020 - mdpi.com
Tridentate ligands are simple low-cost pincers, easy to synthetize, and able to guarantee
stability to the derived complexes. On the other hand, due to its unique mix of structural and …

Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis (N-heterocyclic thione)(SCS-NHT) Pd pincer complex

GE Tyson, K Tokmic, CS Oian, D Rabinovich… - Dalton …, 2015 - pubs.rsc.org
Treatment of 1, 3-bis (3′-butylimidazolyl-1′-yl) benzene diiodide with elemental sulfur in
the presence of a base produced a bis (N-heterocyclic thione)(NHT) pincer ligand precursor …

Iron (II) complexes of a hemilabile SNS amido ligand: Synthesis, characterization, and reactivity

UK Das, SL Daifuku, TE Iannuzzi, SI Gorelsky… - Inorganic …, 2017 - ACS Publications
We report an easily prepared bis (thioether) amine ligand, S Me NHS Me, along with the
synthesis, characterization, and reactivity of the paramagnetic iron (II) bis (amido) …

Mononuclear, dinuclear, and trinuclear iron complexes featuring a new monoanionic SNS thiolate ligand

UK Das, SL Daifuku, SI Gorelsky, I Korobkov… - Inorganic …, 2016 - ACS Publications
The new tridentate ligand, S Me NHS= 2-(2-methylthiophenyl) benzothiazolidine, prepared
in a single step from commercial precursors in excellent yield, undergoes ring-opening on …

Synthesis, characterization, and computational study of three-coordinate SNS-copper (I) complexes based on bis-thione precursors

JR Miecznikowski, MA Lynn, JP Jasinski… - Journal of …, 2014 - Taylor & Francis
A series of tridentate pincer ligands, each possessing two sulfur and one nitrogen donor
(SNS), based on bis-imidazolyl or bis-triazolyl salts were metallated with CuCl2 to give new …

Chemotherapeutic Activities of New η6-p-Cymene Ruthenium(II) and Osmium(II) Complexes with Chelating SS and Tridentate SNS Ligands

DO Ywaya, H Ibrahim, HB Friedrich, MD Bala… - Molecules, 2024 - mdpi.com
A series of new chelating bidentate (SS) alkylimidazole-2-thione-Ru (II)/Os (II) complexes
(3ai, 3aii, 3aiii, 3bii/4aiii, 4bi, 4bii), and the tridentate (SNS) pyridine-2, 6-diylimidazole-2 …

Syntheses and characterization of five-coordinate copper (II) complexes based on tridentate SNS pincer ligand precursors

JR Miecznikowski, MA Lynn, JP Jasinski, W Lo… - Polyhedron, 2014 - Elsevier
A series of tridentate pincer ligands, each possessing two sulfur-and one nitrogen-donor
functionalities (SNS), based on a bis-imidazolyl precursor were metallated with CuCl 2 to …

Electronic and ring size effects of N-heterocyclic carbenes on the kinetics of ligand substitution reactions and DNA/protein interactions of their palladium (II) complexes

RO Omondi, D Jaganyi, SO Ojwach - BioMetals, 2023 - Springer
The synthesis, substitution kinetics and DNA/BSA interactions of four cationic Pd (II)
complexes [Pd (1) Cl] BF4 (Pd1),[Pd (2) Cl] BF4 (Pd2),[Pd (3) Cl] BF4 (Pd3) and [Pd (4) Cl] …