Polyoxometalates (POMs) are a series of molecular metal oxide clusters, which span the two
domains of solutes and solid metal oxides. The unique characters of POMs in structure …

Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …

We demonstrate the reversible in situ photoreduction of molecular junctions of a
phosphomolybdate [PMo12O40] 3− monolayer self-assembled on flat gold electrodes …

The sustainable development of IT-systems requires a quest for novel concepts to address
further miniaturization, performance improvement, and energy efficiency of devices. The …

The exploration of high-nuclearity molecular molybdenum titanium-oxo clusters (MoTOCs)
and their reactivity is a great challenge for polyoxometalate chemistry and materials science …

Polyoxometalate chemistry has made rapid advances in innovative structural chemistry. The
lower valence state and lone electron pair effect of the subgroup-valence heteroatom Te (IV) …

Clusters and oxo-clusters are drawing attention for their amazing physical properties,
especially at the scale of the single molecule. However, chemical methods to organize them …

A systematic study of the condensation reactions of arylarsonic-functionalized [α-
P2W12O48] 14–units in acidic aqueous media identified that the specific presence of an …

This work describes the effects of dodecavanadate anions and phthalocyanine ligands as
well as the identity of lanthanide centers on the charge transport characteristics of …

Two structurally intriguing dysprosium (III)-substituted polyoxometalates,[Dy6 (ampH) 4
(H2O) 23 (ampH2)(PW11O39) 2](1) and [Dy9 (CO3) 3 (ampH) 2 (H2O) 12 (PW10O37) 6] 35 …