Resurgence and advancement of photochemical hydrogen atom transfer processes in selective alkane functionalizations

L Chang, S Wang, Q An, L Liu, H Wang, Y Li… - Chemical …, 2023 - pubs.rsc.org
The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …

C–C bond formation via photocatalytic direct functionalization of simple alkanes

Á Velasco-Rubio, P Martínez-Balart… - Chemical …, 2023 - pubs.rsc.org
The direct functionalization of alkanes represents a very important challenge in the goal to
develop more atom-efficient and clean C–C bond forming reactions. These processes …

Iron-Catalyzed C(Sp3)–H Borylation, Thiolation, and Sulfinylation Enabled by Photoinduced Ligand-to-Metal Charge Transfer

JL Tu, AM Hu, L Guo, W Xia - Journal of the American Chemical …, 2023 - ACS Publications
Catalytic C (sp3)–H functionalization has provided enormous opportunities to construct
organic molecules, facilitating the derivatization of complex pharmaceutical compounds …

Photoelectrochemical oxidative C(sp3)−H borylation of unactivated hydrocarbons

PF Zhong, JL Tu, Y Zhao, N Zhong, C Yang… - Nature …, 2023 - nature.com
Organoboron compounds are of high significance in organic synthesis due to the unique
versatility of boryl substituents to access further modifications. The high demand for the …

External photocatalyst-free CH alkylation of N-sulfonyl ketimines with alkanes under visible light

HY Song, F Xiao, J Jiang, C Wu, HT Ji, YH Lu… - Chinese Chemical …, 2023 - Elsevier
A simple, practical and eco-friendly visible light-induced alkylation of N-sulfonyl ketamine
under metal-, additive-, external photocatalyst-free conditions was developed. This …

Recent Advances in Electron Donor‐Acceptor (EDA)‐Complex Reactions involving Quaternary Pyridinium Derivatives

B Saxena, RI Patel, A Sharma - Advanced Synthesis & …, 2023 - Wiley Online Library
Quaternary pyridinium compounds are valuable intermediates in organic synthesis, which
have gained immense popularity in the synthetic community. The application of transition …

Alkanes in minisci-type reaction under photocatalytic conditions with hydrogen evolution

L Laze, B Quevedo-Flores, I Bosque… - Organic …, 2023 - ACS Publications
We report herein a protocol for the selective activation of C (sp 3)–H bonds based on the
interplay of two readily available organic catalysts and their successful implementation in …

Recent advances in C–H functionalisation through indirect hydrogen atom transfer

FS Meger, JA Murphy - Molecules, 2023 - mdpi.com
The functionalisation of C–H bonds has been an enormous achievement in synthetic
methodology, enabling new retrosynthetic disconnections and affording simple synthetic …

Photoinduced ligand-to-iron charge transfer enabled C (sp 3)–H phosphorylation of hydrocarbons

W Shi, PF Zhong, XK Qi, C Yang, L Guo, W Xia - Green Chemistry, 2023 - pubs.rsc.org
Organophosphine compounds are of high significance in organic synthesis, organometallic
chemistry, and materials science. The high demand for the incorporation of phosphine …

An iron-catalyzed C–S bond-forming reaction of carboxylic acids and hydrocarbons via photo-induced ligand to metal charge transfer

AM Hu, JL Tu, M Luo, C Yang, L Guo… - Organic Chemistry …, 2023 - pubs.rsc.org
Sulfur-containing compounds are commonly present in both natural and synthetic bioactive
molecules. The ability to construct C–S bonds using inexpensive and easily accessible raw …