Over the past decade, the landscape of molecular synthesis has gained major impetus by
the introduction of late-stage functionalization (LSF) methodologies. C–H functionalization …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …

C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

C–H activation has emerged as a transformative tool in molecular synthesis, but until
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …

There is a resurgence of interests in organic electrochemistry, which is generally accepted
as a green synthetic tool. In this context, many electrochemical methods have been …

Electrophotochemistry has enabled arene C− H trifluoromethylation with the Langlois
reagent CF3SO2Na under mild reaction conditions. The merger of electrosynthesis and …

Ammonia is one of the most abundant and simple nitrogen sources with decent stability and
reactivity. Direct insertion of ammonia into a carbon skeleton is an ideal approach to building …

Functionalized oxindole derivatives are widely present in numerous drug-like molecules and
natural products. A green and efficient protocol to access diversely functionalized oxindoles …

Iridium‐catalyzed electrochemical C− H activation was accomplished within a cooperative
catalysis manifold, setting the stage for electrooxidative C− H alkenylations through weak O …